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Umicore CX21

Umicore CX21

Allylchloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]palladium(II)

CAS Number: 478980-03-9

Chemical properties

Chemical formula

C30H41N2ClPd

Empirical formula

[(IPr)Pd(allyl)CI]

Molecular weight

571.54

Metal

Pd

Theoretical metal content

19

Physical state

crystalline

Metal purity

99.95

Your contact person

Ula Rao

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Chinmay Pandya

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Phil Chalabi

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Heidi Heuser

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Yukari Nakada

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Heidi Heuser

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Please order your research quantities at Merck / MilliporeSigma

Applications & references

Description

Palladium catalyzed anaerobic oxidation of secondary alcohols under mild reaction conditions.

Reference: J. Org. Chem. 2011, 76, 1390. (DOI: 10.1021/jo102385u)

 

One-pot oxidation / α-ketone arylation of secondary alcohols.

Reference: J. Org. Chem. 2011, 76, 1390. (DOI: 10.1021/jo102385u)

 

Palladium catalyzed Buchwald-Hartwig-Reaction at room temperature.

Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)

 

α-Arylation of propiophenone.

Reference: Org. Lett. 2002, 4, 4053 (DOI: 10.1021/ol026745m)

 

Intramolecular arylamination step in the total synthesis of cryptocarya alkaloids.

Reference: Synlett 2003, 12, 1871 (DOI: 10.1055/s-2003-41468)

 

Dehalogenation reaction.

Reference: J. Org. Chem. 2004, 69, 3173 (DOI: 10.1021/jo035834p)

 

Suzuki-Miyaura coupling reaction.

 

Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)