Skip to main content Skip to primary navigation

Grubbs Catalyst® M102

Grubbs Catalyst® M102

Dichloro(benzylidene)bis(tricyclohexylphosphine)ruthenium(II)

CAS Number: 172222-30-9

Chemical properties

Chemical formula

C43H72Cl2P2Ru

Empirical formula

Ru(PCy3)2(benzylidene)Cl2

Molecular weight

822.96

Metal

Ru

Theoretical metal content

12

Physical state

powder

Color

purple

Metal purity

99.9

Your contact person

Ula Rao

T: +86 (21) 2411 6843
Email

Chinmay Pandya

T: +91 9867662944
Email

Phil Chalabi

T: +1 (918) 266 4826
Email

Heidi Heuser

T: +49 (6181) 59 2413
Email

Yukari Nakada

T: +81 90 9018 6731
Email

Heidi Heuser

T: +49 (6181) 59 2413
Email

Please order your research quantities at Merck / MilliporeSigma

Applications & references

Description

Formal Synthesis of (-)-Haliclonin A: Stereoselective Construction of an Azabicyclo[3.3.1]nonane Ring System by a Tandem Radical Reaction.

Reference: Org. Lett. 2020, 22, 13, 5046–5050

 

Formylation of a metathesis-derived ansa[4]-ferrocene: a simple route to anticancer organometallics.

Reference: Dalton Trans. 2020, (doi.org/10.1039/D0DT01975E)

 

Aerogels for the separation of asphalt-containing oil–water mixtures and the effect of asphalt stabilizer.

Reference: RSC Adv. 2020,10, 24840-24846

 

Asymmetric total synthesis of the naturally occurring antibiotic Anthracimycin

Reference: Org. Lett. 2020, 22, 14, 5550–5554

 

Sequential two-fold Claisen Rearrangement, One-pot Ring Closing Metathesis and Cross-metathesis as a Route to Substituted Benzo[b]azepine-2-one, Benzo[b]azepine and Benzo[b]oxepine Derivatives.

Reference: Helv Chem Acta 2020 ASAP (doi.org/10.1002/hlca.202000216)

Related products

Hoveyda Grubbs Catalyst® M720

301224-40-8

Precious Metals Chemistry

PMC

Grubbs Catalyst® M220

1255536-61-8[(SIMes)Ru(P(OiPr)3)(Ind)Cl2]

Precious Metals Chemistry

PMC

Grubbs Catalyst® M350

934538-12-2 

Precious Metals Chemistry

PMC

Grubbs Catalyst® M800

1383684-54-5(SIMes)2Ru(Ind)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M110

894423-99-5Ru(iBu-phobane)2(Ind)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M202

536724-67-1(SIMes)Ru(PCy3)(Ind)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M103

194659-03-5Ru(PCy3)2(butenylidene)Cl2

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M722

635679-24-2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M204

246047-72-3(SIMes)Ru(PCy3)(benzylidene)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M206

373640-75-6(SIPr)Ru(PCy3)(benzylidene)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M201

1307233-23-3(SIPr)Ru(PPh3)(Ind)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M104

1190427-44-1Ru(PCy3)2(2-thienylmethylene)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M310

1031262-76-6[(SIMes)Ru(py)(Ind)Cl2]

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M731

1212009-05-6 

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M2001

1352916-84-7

Precious Metals Chemistry

PMC

Grubbs Catalyst® M208

1190427-50-9[(Me)2-IMes]Ru(PCy3)(2-thienylmethylene)Cl2

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M730

1025728-57-7 

Precious Metals Chemistry

PMC

Grubbs Catalyst® M200

340810-50-6[(SIMes)Ru(PPh3)(Ind)Cl2]

Precious Metals Chemistry

PMC

Grubbs Catalyst® M209

1190427-49-6(IMes)Ru(PCy3)(2-thienylmethylene)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M101

250220-36-1Ru(PCy3)2(Ind)Cl2

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M710

1025728-56-6 

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M711

1212008-99-5 

Precious Metals Chemistry

PMC

Grubbs Catalyst® M203

254972-49-1(IMes)Ru(PCy3)(Ind)Cl2

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M700

203714-71-0

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M721

927429-61-6

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M1002

1206687-43-5

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M1001

1632041-02-1

Precious Metals Chemistry

PMC

Grubbs Catalyst® M207

253688-91-4(SIMes)Ru(PCy3)(butenylidene)Cl2

Precious Metals Chemistry

PMC