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Grubbs Catalyst® M202

Grubbs Catalyst® M202

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II)

CAS Number: 536724-67-1

Chemical properties

Chemical formula

C54H69N2Cl2PRu

Empirical formula

(SIMes)Ru(PCy3)(Ind)Cl2

Molecular weight

949.10

Metal

Ru

Theoretical metal content

11

Physical state

powder

Color

red brown

Metal purity

99.9

Your contact person

Ula Rao

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Chinmay Pandya

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Phil Chalabi

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Heidi Heuser

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Yukari Nakada

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Heidi Heuser

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Please order your research quantities at Merck / MilliporeSigma

Applications & references

Description

Cross metathesis of terpenoids.

Reference: WO2012 004414

 

Preparation of α,ω-diacids starting from methyl oleate via self metathesis.

Reference: WO2010 020368

 

Cross metathesis of (E)-ethyl 2-isopropylpenta-2,4-dienoate for the synthesis of pharmaceutical active compounds , in particular rennin inhibitors.

Reference: WO2008 155338

 

Ring closing metathesis in the total synthesis of desoxyepothilone derivatives, which inhibit the growth of tumor cells.

Reference: WO2006 111491

 

Challenging ring closing metathesis.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

 

Enyne cycloisomerization.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

 

Enyne ring closing metathesis.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

 

Cross metathesis of functionalized alkenes.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

 

Ring rearrangement metathesis.

Reference: Eur. J. Org. Chem.  2010, 937 (DOI: 10.1002/ejoc.200901316)