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Grubbs Catalyst® M110

Grubbs Catalyst® M110

Dichlorobis(isobutylphobane)(3-phenyl-1H-indenylidene)ruthenium(II)

CAS Number: 894423-99-5

Chemical properties

Chemical formula

C39H56Cl2P2Ru

Empirical formula

Ru(iBu-phobane)2(Ind)Cl2

Molecular weight

758.79

Metal

Ru

Theoretical metal content

13

Physical state

powder

Color

brown

Metal purity

99.9

Your contact person

Ula Rao

T: +86 (21) 2411 6843
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Chinmay Pandya

T: +91 9867662944
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Phil Chalabi

T: +1 (918) 266 4826
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Heidi Heuser

T: +49 (6181) 59 2413
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Yukari Nakada

T: +81 90 9018 6731
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Heidi Heuser

T: +49 (6181) 59 2413
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Please order your research quantities at Merck / MilliporeSigma

Applications & references

Description

Total synthesis of macrocyclic HCV protease inhibitor with RCM as key step.

Reference: US2009 0163706

 

Ring opening metathesis polymerization.

Reference: Adv. Synth. Catal. 2010, 352, 1934 (DOI: 10.1002/adsc.201000207)

 

Ring closing metathesis forming heterocycles.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

 

Enyne cycloisomerization.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

 

Ethenolysis of methyl oleate.

Reference: Chem. Comm. 2008, 2726 (DOI: 10.1039/B718287B)

 

Self metathesis of terminal alkenes.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)