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Grubbs Catalyst® M102

Grubbs Catalyst® M102

Dichloro(benzylidene)bis(tricyclohexylphosphine)ruthenium(II)

CAS Number: 172222-30-9

Chemical properties

Chemical formula

C43H72Cl2P2Ru

Empirical formula

Ru(PCy3)2(benzylidene)Cl2

Molecular weight

822.96

Metal

Ru

Theoretical metal content

12

Physical state

powder

Color

purple

Metal purity

99.9

Your contact person

Ula Rao

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Chinmay Pandya

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Phil Chalabi

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Heidi Heuser

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Yukari Nakada

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Heidi Heuser

T: +49 (6181) 59 2413
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Please order your research quantities at Merck / MilliporeSigma

Applications & references

Description

Formal Synthesis of (-)-Haliclonin A: Stereoselective Construction of an Azabicyclo[3.3.1]nonane Ring System by a Tandem Radical Reaction.

Reference: Org. Lett. 2020, 22, 13, 5046–5050

 

Formylation of a metathesis-derived ansa[4]-ferrocene: a simple route to anticancer organometallics.

Reference: Dalton Trans. 2020, (doi.org/10.1039/D0DT01975E)

 

Aerogels for the separation of asphalt-containing oil–water mixtures and the effect of asphalt stabilizer.

Reference: RSC Adv. 2020,10, 24840-24846

 

Asymmetric total synthesis of the naturally occurring antibiotic Anthracimycin

Reference: Org. Lett. 2020, 22, 14, 5550–5554

 

Sequential two-fold Claisen Rearrangement, One-pot Ring Closing Metathesis and Cross-metathesis as a Route to Substituted Benzo[b]azepine-2-one, Benzo[b]azepine and Benzo[b]oxepine Derivatives.

Reference: Helv Chem Acta 2020 ASAP (doi.org/10.1002/hlca.202000216)