Umicore Grubbs Catalyst M310

Umicore Grubbs Catalyst M310

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(3-phenyl-1H-inden-1-ylidene)(pyridyl)ruthenium(II)

CAS Number: 1031262-76-6

Product class: M-N, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands, M-C, Grubbs Catalyst® 2nd Generation, SIMes, Pyridyl Ligands

Reaction type: Alkene Metathesis, Cross Metathesis, Enyne Metathesis, Ring Closing Metathesis, Ring Opening Metathesis Polymerization, Self Metathesis

Chemical properties

Chemical formula

C41H41N3Cl2Ru

Empirical formula

[(SIMes)Ru(py)(Ind)Cl2]

Molecular weight

747.71

Metal

Ru

Theoretical metal content

14

Physical state

powder

Color

brown

Metal purity

99.95

Legal information

WO 00 15339, US 10 873 026 and foreign equivalents apply. For use in pharmaceutical applications.

Applications & references

Ring closing metathesis in acetic acid.

Reference: Beilstein J. Org. Chem. 2010, 6, 1188 (DOI:10.3762/bjoc.6.136)

 

Ring closing metathesis of acrylates.

Reference: Beilstein J. Org. Chem. 2010, 6, 1188 (DOI:10.3762/bjoc.6.136)

 

Ring closing en-yne metathesis.

Reference: Beilstein J. Org. Chem. 2010, 6, 1188 (DOI:10.3762/bjoc.6.136)

 

Cross metathesis of functionalized allylic alcohols.

Reference: Beilstein J. Org. Chem. 2010, 6, 1188 (DOI:10.3762/bjoc.6.136)

 

Ring opening metathesis polymerization.

Reference: Eur. J. Org. Chem. 2009, 655 (DOI: 10.1002/ejoc.200800973)