Umicore Grubbs Catalyst M201

Umicore Grubbs Catalyst M201

[1,3-Bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]dichloro(3-phenyl-1H-inden-1-ylidene)(triphenylphosphine) ruthenium(II)

CAS Number: 1307233-23-3

Product class: M-P, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands, M-C, Grubbs Catalyst® 2nd Generation, SIPr, Phosphorus Ligands - Achiral

Reaction type: Alkene Metathesis, Cross Metathesis, Enyne Metathesis, Ring Closing Metathesis, Self Metathesis

Chemical properties

Chemical formula

C60H63N2Cl2PRu

Empirical formula

(SIPr)Ru(PPh3)(Ind)Cl2

Molecular weight

1015.21

Metal

Ru

Theoretical metal content

10

Physical state

powder

Color

brown

Metal purity

99.95

Legal information

WO 2000 15339, US 10 873 026 and foreign equivalents apply. For use in pharmaceutical applications.

Applications & references

Ring closing en-yne metathesis.

Reference: Chem. Comm. 2011, 47, 5022 (DOI: 10.1039/C1CC10741K)

 

Cross metathesis of terminal alkenes with acrylates.

Reference: Chem. Comm. 2011, 47, 5022 (DOI: 10.1039/C1CC10741K)

 

Ring closing metathesis.

Reference: Chem. Comm. 2011, 47, 5022 (DOI: 10.1039/C1CC10741K)

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Heidi Heuser

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Xiaofang Bi

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Heidi Heuser

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