Umicore Grubbs Catalyst M110

Umicore Grubbs Catalyst M110

Chemical properties

Chemical formula

C39H56Cl2P2Ru

Empirical formula

Ru(iBu-phobane)2(Ind)Cl2

Molecular weight

758.79

Metal

Ru

Theoretical metal content

13

Physical state

powder

Color

brown

Metal purity

99.95

Legal information

WO 2007 010453 applies.

Applications & references

Total synthesis of macrocyclic HCV protease inhibitor with RCM as key step.

Reference: US2009 0163706

 

Ring opening metathesis polymerization.

Reference: Adv. Synth. Catal. 2010, 352, 1934 (DOI: 10.1002/adsc.201000207)

 

Ring closing metathesis forming heterocycles.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

 

Enyne cycloisomerization.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

 

Ethenolysis of methyl oleate.

Reference: Chem. Comm. 2008, 2726 (DOI: 10.1039/B718287B)

 

Self metathesis of terminal alkenes.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)