Umicore CX23

Umicore CX23

Chemical properties

Chemical formula

C30H43N2ClPd

Empirical formula

(SIPr)Pd(allyl)Cl

Molecular weight

573.56

Metal

Pd

Theoretical metal content

19

Physical state

crystalline

Color

yellow

Metal purity

99.95

Applications & references

α-Arylation of ketones.

Reference: Org. Lett. 2002, 4, 4053 (DOI: 10.1021/ol026745m); Adv. Synth. Catal. 2012, 354, 377 (DOI: 10.1002/adsc.201100669)

 

Intramolecular arylamination step in the synthetic approach of cryptocarya alkaloids.

Reference: Synlett 2003, 12, 1871 (DOI: 10.1021/jo035834p)

 

Suzuki-Miyaura coupling reaction.

Reference: J. Org. Chem. 2004, 69, 3173

 

Buchwald-Hartwig coupling reactions.

Reference: J. Am. Chem. Soc. 2006, 128, 4101 (DOI: 10.1021/ja057704z)

 

α-Heteroarylation of ketone enolates.

Reference: J. Org. Chem. 2010, 75, 5316 (DOI: 10.1021/jo100623d)

 

Palladium catalyzed anaerobic oxidation of secondary alcohols under mild reaction conditions.

Reference: J. Org. Chem. 2011, 76, 1390. (DOI: 10.1021/jo102385u)

 

Palladium catalyzed Buchwald-Hartwig- Reaction at room temperature.

Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)

 

 

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