Umicore CX200

Di-µ-chlorobis(1-tert-butyl-1H-inden-1-yl)dipalladium(II)

CAS Number: 1779569-01-5

Metal:

• Palladium

Product class:

• Homogeneous CatalystsHazari Catalyst
• Homogeneous CatalystsM-CIndenyl Ligands

Application:

• Agrochemicals
• Electronics
• Fine Chemicals
• Homogeneous Catalysts
• Pharmaceuticals

Reaction type:

• AminationBuchwald-Hartwig Aminaton
• Cross Coupling Reactions with ArenesSuzuki-Miyaura Coupling Reaction

Applications & references

Suzuki-Miyaura coupling reaction catalyzed by an in situ generated solution of [Pd(cinnamyl)Cl]₂ and IPr and an in situ generated solution of our Pd-cat. and IPr.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

Suzuki-Miyaura coupling reaction of 2-chloro-4,6-dimethoxyprimidine and benzofuran-2-boronic acid catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

Suzuki-Miyaura coupling reaction of 2-chloro-1H-benzimidazole and 3-thiophene boronic acid catalyzed by an in situ precatalyst generated from Umicore our Pd-cat. and SPhos.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

Suzuki-Miyaura coupling reaction of 2-methoxy chlorobenzene and morpholine catalyzed by an in situ precatalyst generated from our Pd-cat. and RuPhos.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

Suzuki-Miyaura coupling reaction of 3-acetylpyridine and 3-chloropyridine catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

Suzuki-Miyaura coupling reaction of 4-chloroanisole and potassium isopropyltrifluoroboronate catalyzed by an in situ precatalyst generated from our Pd-cat. and P(^tBu)₃.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

Hiyama-Denmark Reactions of 4-(trifluoromethyl)chlorobenzene and 4-(methoxy)phenyl silanolate catalyzed by in situ precatalysts generated from our Pd-cat. and different ligands.

Reference: Org. Lett. 2016, 18, 5784 (DOI: 10.1021/acs.orglett.6b02330)