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Umicore CX200

Umicore CX200

Chemical properties

Chemical formula

C26H30Cl2Pd2

Empirical formula

[Pd(1-tBu-Ind)Cl]2

Molecular weight

626.27

Metal

Pd

Theoretical metal content

34

Metal purity

99.95

Applications & references

Description

Suzuki-Miyaura coupling reaction catalyzed by an in situ generated solution of [Pd(cinnamyl)Cl]2 and IPr and an in situ generated solution of our Pd-cat. and IPr.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

 

Suzuki-Miyaura coupling reaction of 2-chloro-4,6-dimethoxyprimidine and benzofuran-2-boronic acid catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

 

Suzuki-Miyaura coupling reaction of 2-chloro-1H-benzimidazole and 3-thiophene boronic acid catalyzed by an in situ precatalyst generated from Umicore our Pd-cat. and SPhos.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

 

Suzuki-Miyaura coupling reaction of 2-methoxy chlorobenzene and morpholine catalyzed by an in situ precatalyst generated from our Pd-cat. and RuPhos.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

 

Suzuki-Miyaura coupling reaction of 3-acetylpyridine and 3-chloropyridine catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

 

Suzuki-Miyaura coupling reaction of 4-chloroanisole and potassium isopropyltrifluoroboronate catalyzed by an in situ precatalyst generated from our Pd-cat. and P(tBu)3.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

 

Hiyama-Denmark Reactions of 4-(trifluoromethyl)chlorobenzene and 4-(methoxy)phenyl silanolate catalyzed by in situ precatalysts generated from our Pd-cat. and different ligands.

Reference: Org. Lett. 2016, 18, 5784 (DOI: 10.1021/acs.orglett.6b02330)