Pd(PEPPSI)(SIPr)

Pd(PEPPSI)(SIPr)

Dichloro[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidinylidene](3-chloropyridyl)palladium(II)

CAS Number: 927706-57-8

Product class: M-P, Homogeneous Catalysts, M-N, N-Heterocyclic Carbene Ligands, M-C, SIPr, PEPPSI Ligands, Pyridyl Ligands, Bidentate Ligands

Reaction type: Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, C-H Activation, Kumada Coupling Reaction, Suzuki-Miyaura Coupling Reaction

Chemical properties

Chemical formula

C32H42N3Cl3Pd

Empirical formula

[(SIPr)Pd(3-Cl-py)Cl2]

Molecular weight

681.48

Metal

Pd

Theoretical metal content

16

Physical state

crystalline

Color

yellow

Metal purity

99.95

Legal information

US 6 316 380, WO 2004 014550 and foreign equivalents apply. Quantities up to 1kg are exclusively sold by Sigma Aldrich Catalogue.

Applications & references

Buchwald-Hartwig coupling reactions.

Reference: Chem. Eur. J. 2008, 14, 2443 (DOI: 10.1002/chem.200701621)

 

C-H functionalization reactions.

 

Reference: Tetrah. Lett. 2012, 53, 1173 (DOI: 10.1016/j.tetlet.2011.12.108)

 

Kumada-Tamao-Corriu reactions.

Reference: Chem. Eur. J. 2007, 13, 150 (DOI: 10.1002/chem.200601360)

 

Suzuki-Miyaura coupling reaction.

Reference: Adv. Synth. Catal. 2009, 351, 1575 (DOI: 10.1002/adsc.200900098)

 

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