[(IPr)AuCl]

[(IPr)AuCl]

Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I)

CAS Number: 852445-83-1

Product class:

Reaction type:

Chemical properties

Chemical formula

C27H36N2ClAu

Empirical formula

[(IPr)AuCl]

Molecular weight

621.01

Metal

Au

Theoretical metal content

32

Physical state

powder

Color

white

Metal purity

99.95

Applications & references

Rearrangement of allylic acetates.

Reference: Org. Lett. 2007, 9, 2653 (DOI: 10.1021/ol070843w); Organomet. 2011, 30, 5463 (DOI: 10.1021/om200705y)

 

Olefin cyclopropanation.

Reference: Tetrah. 2009, 65, 1790 (DOI: 10.1016/j.tet.2008.10.114)

 

Alkane C-H-bond functionalization.

Reference: Organomet. 2006, 25, 2237 (DOI: 10.1021/om0507474)

 

Carboxylation of C-H bonds.

Reference: J. Am. Chem. Soc. 2010, 132, 8858 (DOI: 10.1021/ja103429q)

 

Hydration of alkynes.

Reference: J. Am. Chem. Soc. 2009, 131, 448 (DOI: 10.1021/ja809403e)

 

Hydroarylation-aromatization of arenes-diynes.

Reference: Organomet. 2012, 31, 644 (DOI: 10.1021/om200946m)

 

Cyclization of aryl-substituted propargylamides.

Reference: Eur. J. Org. Chem. 2011, 4595 (DOI: 10.1002/ejoc.201100342)

 

Cycloisomerization of enyl etsters and allenyl esters.

Reference: Chem. Eur. J. 2009, 15, 3243 (DOI: 10.1002/chem.200801387)

 

Tandem hydroamination-hydroarylation reaction.

Reference: Org. Lett. 2007, 9, 2645 (DOI: 10.1021/ol070814l)

 

Tandem 1,2-indole migration and aura-Nazarov cyclization reaction of 3-propargylindoles.

Reference: Beilstein J. Org. Chem. 2011, 7, 786 (DOI:10.3762/bjoc.7.89)

 

Cascade insertion and cyclization of water with substituted phenyldiazoacetates.

Reference: Beilstein J. Org. Chem. 2011, 7, 631 (DOI:10.3762/bjoc.7.74)

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