Chiralyst Ru928

Chiralyst Ru928

Chloro[(S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](benzene)ruthenium(II) chloride

CAS Number: 126251-92-1

Metal:

Product class:

Application:

Reaction type:

Chemical properties

Chemical formula

C50H38Cl2P2Ru

Empirical formula

[RuCl(benzene)(S)-BINAP]Cl

Molecular weight

827.77

Metal

Ru

Theoretical metal content

12

Physical state

powder

Color

yellow

Metal purity

99.95

Applications & references

Synthesis of α-arylpropionic acids by catalytic asymmetrical hydrogenation of α-arylpropenioc acids starting from α-arylketones.

Reference: WO1992 09552

 

Asymmetric hydrogenation of a five-membred α,ß-unsaturated carbonyl component.

Reference: J. Org. Chem. 1995, 60, 857 (DOI: 10.1021/jo00107a014)

 

Asymmetric hydrogenation of a functionalized diketone.

Reference: J. Org. Chem. 1995, 60, 857 (DOI: 10.1021/jo00107a014)

 

Asymmetric hydrogenation of α-ketoester.

Reference: J. Org. Chem. 1994, 59, 3064 (DOI: 10.1021/jo00090a026)

 

Oxidation of cis-1,2-cyclohexanedimethanol by hydrogen transfer reaction.   

Reference: J. Organomet. Chem. 1994, 473, 253 (DOI: 10.1016/0022-328X(94)80125-8)

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