Chiralyst Ru637
Chiralyst Ru637
[((S,S)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)(p-cymene)ruthenium(II)
CAS Number: 192139-90-5
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Applications & references
Synthesis of optically active 4-hydroxy-2,6,6-trimethyl-cyclohex-3-enone derivatives via enantioselective transfer hydrogenation of the corresponding enolethers for the production of (3S,3’S)-astaxantin.
Reference: WO2008 116714
Asymmetric transfer hydrogenation of imines to amines using isopropanol and formic acid as hydrogen source.
Reference: WO2010 022518
Asymmetric transfer hydrogenation of benzil with formic acid and triethylamine.
Reference: Org. Lett. 1999, 1, 1119 (DOI: 10.1021/ol990226a); Org. Synth. 2005, 82, 10 (DOI: 10.15227/orgsyn.082.0010)
Reduction of aliphatic 1,3-diketones.
Reference: Org. Lett. 2002, 4, 1263 (DOI: 10.1021/ol025527q)
Asymmetric transfer hydrogenation of an alkynone derivative with isopropanol as hydrogen source in the total synthesis of zaragozic acids.
Reference: Chem. Eur. J. 2011, 17, 3335 (DOI: 10.1002/chem.201003399)
Asymmetric transfer hydrogenation of functionalized cyclic ketones.
Reference: Org. Synth. 2005, 82, 10 (DOI: 10.15227/orgsyn.082.0010 )
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