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Umicore HS161

Umicore HS161

Trimethyl(methylcyclopentadienyl)platinum(IV)

CAS Number: 94442-22-5

Chemical properties

Chemical formula

C9H16Pt

Empirical formula

[Pt(Me)3(CpMe)]

Molecular weight

319.31

Metal

Pt

Theoretical metal content

61

Physical state

powder

Color

white

Metal purity

99.95

Your contact person

Don Zeng

T: +1 (714) 777 3737
Email

Julia Pullmann

T: +49 (6181) 59 2794
Email

Dirk Rickert

T: +49 (6181) 59 3098
Email

Yukari Nakada

T: +81 90 9018 6731
Email

Julia Pullmann

T: +49 (6181) 59 2794
Email

Dirk Rickert

T: +49 (6181) 59 3098
Email

Please order your research quantities at Merck / MilliporeSigma

Applications & references

Description

Platinum nanoparticles are formed by gas phase loading of the volatile platinum compounds on metal-organic frameworks and by subsequent reduction with 100 bar hydrogen. For instance, the Pt component shows high catalytic activity in solvent-free and base-free oxidation of alcohols in air at room temperature.

Reference: Chem. Eur. J. 2008, 14, 8204 (DOI: 10.1002/chem.200801043)

 

Trimethyl(methylcyclopentadienyl)platinum(IV) as an effective photoinitiator for hydrosilylation reactions.

Reference: Inorg. Chem. 2004, 43, 6869 (DOI: 10.1021/ic0496222)

 

Trimethyl(methylcyclopentadienyl)platinum(IV) is often used as ALD and CVD precursor.

Reference:  WO2010 033318 ; Electrochimica Acta 2012, 75, 101 (10.1016/j.electacta.2012.04.084)