Umicore HS161

Trimethyl(methylcyclopentadienyl)platinum(IV)

[Pt(Me)3(CpMe)]

Product Number : 3000034580     CAS Number : 94442-22-5
Product Keywords :

Chemical properties

Chemical formula

C9H16Pt

Empirical formula

[Pt(Me)3(CpMe)]

Molecular weight [g/mol]

319.31

Metal

Pt

Theoretical metal content [%]

61

Physical state

powder

Color

white

Metal purity [%]

99.95

Safety Information

H302, H312, H332, H315, H319, H400, H410

Handling & storage information

Handling information

Ensure good ventilation and exhaustion at the workplace.


Storage information

Do not store above 4°C (39°F). Store in a tightly closed original container under dry inert gas protected from direct sunlight in a dry, cool and well-ventilated area.

Applications & References

Platinum nanoparticles are formed by gas phase loading of the volatile platinum compounds on metal-organic frameworks and by subsequent reduction with 100 bar hydrogen. For instance, the Pt@MOF-177 shows high catalytic activity in solvent-free and base-free oxidation of alcohols in air at room temperature.

Reference:  Chem. Eur. J. 2008, 14, 8204 (DOI: 10.1002/chem.200801043)

Trimethyl(methylcyclopentadienyl)platinum(IV) as an effective photoinitiator for hydrosilylation reactions.

Reference:  Inorg. Chem. 2004, 43, 6869 (DOI: 10.1021/ic0496222)

Trimethyl(methylcyclopentadienyl)platinum(IV) is often used as ALD and CVD precursor.

Reference:  WO2010 033318; Electrochimica Acta 2012, 75, 101 (10.1016/j.electacta.2012.04.084)

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