Umicore CX23

Allylchloro[1,3-bis-(2,6-diisopropylphenyl)imidazol-2-idinylidene]palladium(II)

(SIPr)Pd(allyl)Cl

Product Number : 3000034526     CAS Number : 478980-01-7
Product Keywords :

Chemical properties

Chemical formula

C30H43N2ClPd

Empirical formula

(SIPr)Pd(allyl)Cl

Molecular weight [g/mol]

573.56

Metal

Pd

Theoretical metal content [%]

19

Physical state

crystalline

Color

yellow

Metal purity [%]

99.95

Safety Information

H302, H312, H332, H315, H319, H413

Handling & storage information

Handling information

Ensure good ventilation and exhaustion at the workplace.


Storage information

Do not store above 25°C (77°F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.

Applications & References

Legal information

US 6 316 380, WO 2004 014550 and foreign equivalents apply.

a-Arylation of ketones.

Reference: Org. Lett. 2002, 4, 4053 (DOI: 10.1021/ol026745m); Adv. Synth. Catal. 2012, 354, 377 (DOI: 10.1002/adsc.201100669)

Intramolecular arylamination step in the synthetic approach of cryptocarya alkaloids.

Reference: Synlett 2003, 12, 1871 (DOI: 10.1021/jo035834p)

Suzuki-Miyaura coupling reaction.

Reference: J. Org. Chem. 2004, 69, 3173

Buchwald-Hartwig coupling reactions.

Reference: J. Am. Chem. Soc. 2006, 128, 4101 (DOI: 10.1021/ja057704z)

a-Heteroarylation of ketone enolates.

Reference: J. Org. Chem. 2010, 75, 5316 (DOI: 10.1021/jo100623d)

Palladium catalyzed anaerobic oxidation of secondary alcohols under mild reaction conditions.

Reference: J. Org. Chem. 2011, 76, 1390. (DOI: 10.1021/jo102385u)

Palladium catalyzed Buchwald-Hartwig- Reaction at room temperature.

Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)

 

 

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