Umicore CX42

Umicore CX42

Dichloro(di-ยต-chloro)bis[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]dipalladium(II)

CAS Number: 627878-09-5

Product class: Homogeneous Catalysts, M-C, N-Heterocyclic Carbene Ligands, SIPr, M-P, Bidentate Ligands

Reaction type: Amination, Buchwald-Hartwig Aminaton, CH-Activation, Cross Coupling Reactions with Arenes, Kumada Coupling Reaction, Oxidation, Suzuki-Miyaura Coupling Reaction

Chemical properties
Chemical formula

C54H76N4Cl4Pd2

Empirical formula

[(SIPr)PdCl2]2

Molecular weight

1135.87

Metal

Pd

Theoretical metal content

19

Physical state

powder

Color

orange

Metal purity

99.95

Legal information

US 6 316 380, WO 2004 014550 and foreign equivalents apply.

Applications & references

Intramolecular direct arylation of aryl chlorides.

Reference: Synth. Comm. 2011, 41, 41 (DOI: 10.1080/00397910903531755)

Hydroarylation reaction.

Reference: US2009 0069580; Tetrah. 2009, 65, 5074 (DOI: 10.1016/j.tet.2009.03.096)

Kumada coupling reactions.

Reference: Organomet. 2009, 28, 2915 (DOI: 10.1021/om900072f) 

Request a quote or MSDS

Get in touch

Related products

Umicore CX135 - Pd(tBuXPhos)G3

PMC

1447963-75-8Pd(tBuXPhos)[2-(2'-amino-1,1'-biphenyl)](Ms)

Precious Metals Chemistry

Umicore CX122 - Pd(XPhos)G2

PMC

1310584-14-5Pd(XPhos)[2-(2'-amino-1,1'-biphenyl)]Cl

Precious Metals Chemistry

[Pd(cod)Cl2]

PMC

12107-56-1[Pd(cod)Cl2]

Precious Metals Chemistry

[Pd(OAc)2]3

PMC

3375-31-3[Pd(OAc)2]3

Precious Metals Chemistry

Umicore CX33

PMC

1380314-24-8[(IPr*)Pd(cinnamyl)Cl]

Precious Metals Chemistry

Umicore CX72

PMC

29934-17-6[Pd(PCy3)2Cl2]

Precious Metals Chemistry

Umicore CX98

PMC

205319-06-8[Pd(DPEphos)Cl2]

Precious Metals Chemistry

Umicore CX73

PMC

13965-03-2[Pd(PPh3)2Cl2]

Precious Metals Chemistry

Umicore CX76

PMC

59840-38-9[Pd(PCy3)2(OAc)2]

Precious Metals Chemistry

[Pd(allyl)Cl]2

PMC

12012-95-2[Pd(allyl)Cl]2

Precious Metals Chemistry

Umicore CX71

PMC

185812-86-6[PdBr[P(tBu3)]]2

Precious Metals Chemistry

Umicore CX23

PMC

478980-01-7(SIPr)Pd(allyl)Cl

Precious Metals Chemistry

Umicore CX62

PMC

1708984-17-1[Pd(dippf)(vs)tol]

Precious Metals Chemistry

Umicore CX22

PMC

478980-04-0[(IMes)Pd(allyl)Cl]

Precious Metals Chemistry

Pd(PEPPSI)IPr

PMC

905459-27-0[(IPr)Pd(3-Cl-py)Cl2]

Precious Metals Chemistry

Fu catalyst

PMC

53199-31-8[Pd(P(tBu3))2]

Precious Metals Chemistry

Umicore CX84

PMC

887919-35-9[Pd(amphos)2Cl2]

Precious Metals Chemistry

Umicore CX93

PMC

72287-26-4[Pd(dppf)Cl2]

Precious Metals Chemistry

Pd(PEPPSI)(SIPr)

PMC

927706-57-8[(SIPr)Pd(3-Cl-py)Cl2]

Precious Metals Chemistry

Umicore CX96

PMC

95408-45-0[Pd(dtbpf)Cl2]

Precious Metals Chemistry

Umicore CX41

PMC

444910-17-2[(IPr)PdCl2]2

Precious Metals Chemistry

Pd-Tetrakis

PMC

14221-01-3[Pd(PPh3)4]

Precious Metals Chemistry

Umicore CX21

PMC

478980-03-9[(IPr)Pd(allyl)CI]

Precious Metals Chemistry