Umicore CX42

Dichloro(di-µ-chloro)bis[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]dipalladium(II)

CAS Number: 627878-09-5

Product class: M-P, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands, M-C, SIPr, Bidentate Ligands

Reaction type: Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, CH-Activation, Kumada Coupling Reaction, Oxidation, Suzuki-Miyaura Coupling Reaction

Legal information

US 6 316 380, WO 2004 014550 and foreign equivalents apply.

Applications & references

Intramolecular direct arylation of aryl chlorides.

Reference: Synth. Comm. 2011, 41, 41 (DOI: 10.1080/00397910903531755)

Hydroarylation reaction.

Reference: US2009 0069580; Tetrah. 2009, 65, 5074 (DOI: 10.1016/j.tet.2009.03.096)

Kumada coupling reactions.

Reference: Organomet. 2009, 28, 2915 (DOI: 10.1021/om900072f)