Umicore CX42

Umicore CX42

Dichloro(di-ยต-chloro)bis[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]dipalladium(II)

CAS Number: 627878-09-5

Product class: Homogeneous Catalysts, M-C, N-Heterocyclic Carbene Ligands, SIPr, M-P, Bidentate Ligands

Reaction type: Amination, Buchwald-Hartwig Aminaton, CH-Activation, Cross Coupling Reactions with Arenes, Kumada Coupling Reaction, Oxidation, Suzuki-Miyaura Coupling Reaction

Chemical properties
Chemical formula

C54H76N4Cl4Pd2

Empirical formula

[(SIPr)PdCl2]2

Molecular weight

1135.87

Metal

Pd

Theoretical metal content

19

Physical state

powder

Color

orange

Metal purity

99.95

Legal information

US 6 316 380, WO 2004 014550 and foreign equivalents apply.

Applications & references

Intramolecular direct arylation of aryl chlorides.

Reference: Synth. Comm. 2011, 41, 41 (DOI: 10.1080/00397910903531755)

Hydroarylation reaction.

Reference: US2009 0069580; Tetrah. 2009, 65, 5074 (DOI: 10.1016/j.tet.2009.03.096)

Kumada coupling reactions.

Reference: Organomet. 2009, 28, 2915 (DOI: 10.1021/om900072f) 

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