Umicore CX42
Dichloro(di-μ-chloro)bis[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]dipalladium(II)
[(SIPr)PdCl2]2
Chemical properties
Chemical formula
C54H76N4Cl4Pd2
Empirical formula
[(SIPr)PdCl2]2
Molecular weight [g/mol]
1135.87
Metal
Pd
Theoretical metal content [%]
19
Physical state
powder
Color
orange
Metal purity [%]
99.95
Safety Information
H302, H312, H332, H315, H319, H413
Handling & storage information
Handling information
Ensure good ventilation and exhaustion at the workplace.
Storage information
Do not store above 25°C (77°F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.
Applications & References
Legal information
US 6 316 380, WO 2004 014550 and foreign equivalents apply.
Intramolecular direct arylation of aryl chlorides.
Reference: Synth. Comm. 2011, 41, 41 (DOI: 10.1080/00397910903531755)
Hydroarylation reaction.
Reference: US2009 0069580; Tetrah. 2009, 65, 5074 (DOI: 10.1016/j.tet.2009.03.096)
Kumada coupling reactions.
Reference: Organomet. 2009, 28, 2915 (DOI: 10.1021/om900072f)
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Umicore CX33
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Umicore HS161
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Umicore Hoveyda-Grubbs Catalyst MZ1c (C633)
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Umicore Hoveyda-Grubbs Catalyst MZ2c (C675)
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(SIMes)2Ru(butenylidene)Cl2
Umicore Grubbs Catalyst M80a (C875-bis)
508172-19-8(SIMes)2Ru(benzylidene)Cl2
RhI3
15492-38-3RhI3
Chiralyst Ru1042
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Umicore Grubbs Catalyst M23 (C947)
1817799-58-8(SIMes)Ru[PPh2(OPh)](Ind)Cl2
Umicore Grubbs Catalyst M1b (C801)
194659-03-5Ru(PCy3)2(butenylidene)Cl2
Umicore Hoveyda-Grubbs Catalyst M70 (C601)
203714-71-0
Umicore Grubbs Catalyst M2a (C848)
246047-72-3(SIMes)Ru(PCy3)(benzylidene)Cl2
Umicore Grubbs Catalyst M2b (C827)
253688-91-4(SIMes)Ru(PCy3)(butenylidene)Cl2
Umicore Grubbs Catalyst M24 (C885)
2016028-91-2(SIMes)Ru[PPh2(OMe)](Ind)Cl2
Umicore Hoveyda-Grubbs Catalyst M72 (C627)
301224-40-8
Umicore Hoveyda-Grubbs Catalyst M72 SIPr (C711)
635679-24-2
Umicore Grubbs Catalyst M52
1014701-61-1
Umicore Grubbs Catalyst M1a (C823)
172222-30-9Ru(PCy3)2(benzylidene)Cl2
Umicore Grubbs Catalyst M33i
1203589-76-7
Umicore Grubbs Catalyst M31 SIPr
1304756-39-5(SIPr)Ru(py)(Ind)Cl2
Umicore CX121 - Pd(SPhos)G2
1375325-64-6Pd(SPhos)[2-(2'-amino-1,1'-biphenyl)]Cl
Umicore CX98
205319-06-8[Pd(DPEphos)Cl2]
Pt(KNS) solution
13815-39-9K2[Pt(NO2)4] sol. in sulphuric acid
[Pd(HOCH2CH2NH2)4](NO3)2 sol.
[Pd(HOCH2CH2NH2)4](OAc)2 sol.
473828-45-4[Pd(HOCH2CH2NH2)4](OAc)2 sol.
Pt(TAHC)
123439-82-7[Pt(NH3)4](HCO3)2
Pd/Pt EA solution type A14
68133-90-4
Pd(TAA) solution
61495-96-3[Pd(NH3)4](OAc)2 solution
Pd nitrate solution type P
10102-05-3Pd(NO3)2 solution type P
Rh nitrate solution low acid
10139-58-9Rh(NO3)3 solution low acid
Cisplatin
15663-27-1[Pt(NH3)2Cl2]
Elyst Pt50 0690
7440-06-4Pt/Co alloy on carbon black
Chiralyst Ru918
944451-29-0[RuCl(p-cymene)(S)-SEGPHOS)]Cl
WOCl4
13520-78-0WOCl4
Umicore DeRu40
32992-96-4Ru(EtCp)2
MTO
70197-13-6CH3ReO3
W(CO)6
14040-11-0W(CO)6
Elyst Pt20 0390
7440-06-4Pt on carbon black
BTBMW
406462-43-9W(tBuN)2(NMe2)2
Tungsten(V) chloride el. grade
13470-14-9WCl5
Umicore CX34
1454680-44-4[(IPr*OMe)Pd(cinnamyl)Cl]
Umicore CX71
185812-86-6[PdBr[P(tBu3)]]2
Mo(CO)6
13939-06-5Mo(CO)6
Pt Black
7440-06-4Pt
Rh sulfate solution type PLA
10489-46-0Rh2(SO4)3 solution
Pt EA solution type CC
68133-90-4(HOCH2CH2NH3)2[Pt(OH)6] sol.
Pd sulfate solution type S
13566-03-5PdSO4 solution type S
Carboplatin
41575-94-4[Pt(NH3)2(cbdc)]
Oxaliplatin
61825-94-3[Pt((R,R)-dach)(ox)]
Umicore CX82
104889-13-6[Pd(P(tBu)Cy2)2Cl2]
Pt-Tetrakis
14221-02-4[Pt(PPh3)4]
Rh(2-eh) solution type N
20845-92-5[Rh(C8H15O2)3] solution
Pt nitrate solution type H
18496-40-7Pt(NO3)2 solution type H
Pt(TAN) solution low Cl
20634-12-2[Pt(NH3)4](NO3)2 solution
Pt nitrate solution type N
18496-40-7Pt(NO3)2 solution type N
Pd(TAN) solution type C
13601-08-6[Pd(NH3)4](NO3)2 solution
Arsenic(III) oxide
1327-53-3As2O3
[(IMes)AuCl]
852445-81-9[(IMes)AuCl]
CPA hydrate
26023-84-7H2[PtCl6] x n H2O
Chiralyst P468
99326-34-8[Rh(cod)2]CF3SO3
[Ru(SL-M001-1)(C7H11)(N-AcCN)]BF4.2HBF4
Wilkinson's catalyst
14694-95-2Rh(PPh3)3Cl
PDMAT
19824-59-0Ta(Me2N)5
Rh(OAc)3
42204-14-8Rh(OAc)3
[Pd(OOCtBu)2]3
106224-36-6
[Pd(OOCtBu)2]3
Elyst Pt50 0380
7440-06-4Pt on carbon black
Umicore Grubbs Catalyst M32h
1416427-09-2
Chiralyst P280
50982-12-2[Ru(cod)Cl2]n
Pt nitrate solution type HNA
18496-40-7Pt(NO3)2 solution type HNA
Ru(PPh3)2(Ind)Cl
1360949-97-8Ru(PPh3)2(Ind)Cl
CCTBA
56792-69-9Co2(CO)6[HCC(C(CH3)3]
Umicore CX62
1708984-17-1[Pd(dippf)(vs)tol]
Elyst Pt50 0550
7440-06-4Pt on carbon black
TMGa
1445-79-0GaMe3
Umicore Grubbs Catalyst M91
1415725-62-0
[Ru(Cp)(CO)2]2
12132-87-5[Ru(Cp)(CO)2]2
Umicore HS432
400758-55-6[(ICy)Pt(vs)]
Umicore HS425
849830-54-2[(IPr)Pt(vs)]
Chiralyst Ru867
1016168-44-7[Ru(SL-J002-1)(C7H11)(N-AcCN)]BF4
Chiralyst Ru1013
942042-51-5[Ru(SL-T001-1)(C7H11)(N-AcCN)]BF4
Chiralyst Ru929
145926-28-9[RuCl(p-cymene)(R)-BINAP]Cl
Chiralyst Rh740
894423-88-2[Rh[(R,R)-DIPAMP](nbd)]BF4
Chiralyst Rh757
71423-54-6[Rh[(S,S)-DIPAMP](cod)]BF4
Chiralyst Rh986
673458-84-9[Rh(SL-T001-1)(cod)]BF4
Umicore Grubbs Catalyst M35
934538-12-2
Umicore Grubbs Catalyst M81
1228169-92-3
[Au(en)2]Cl3
15278-22-5[Au(en)2]Cl3
[Ir(cod)2]BF4
35138-23-9[Ir(cod)2]BF4
Umicore CX97
205319-10-4[Pd(Xantphos)Cl2]
Umicore CX83
1444507-24-7[Pd[P(tBu2)(nBu)]2Cl2]
Umicore HS221
68478-92-2Pt(vs)hc
CAA hydrate
27988-77-8H[AuCl4] x n H2O
Umicore Grubbs Catalyst M92
1415725-73-3
Rh2O3
12036-35-0Rh2O3
RhCl3 x n H2O
20765-98-4RhCl3 x n H2O
Rh Black
7440-16-6Rh
PdO x n H2O
64109-12-2PdO x n H2O
Pd(TAHC)
134620-00-1[Pd(NH3)4](HCO3)2
Pd(TAC) hydrate
13815-17-3[Pd(NH3)4]Cl2 x n H2O
Pd sulfate solution type P
13566-03-5PdSO4 solution type P
Pd(TAS) solution
13601-06-4[Pd(NH3)4]SO4 solution
PdCl2
7647-10-1PdCl2
Adams' catalyst
52785-06-5PtO2 x n H2O
Pt(TAC) hydrate
13933-33-0[Pt(NH3)4]Cl2 x n H2O
CPA solution 25
16941-12-1H2[PtCl6] solution
CPA hydrate
26023-84-7H2[PtCl6] x n H2O
Umicore Hoveyda-Grubbs Catalyst M71
1025728-56-6
Umicore Grubbs Catalyst M93
1415725-68-6
Umicore Grubbs Catalyst M31
1031262-76-6[(SIMes)Ru(py)(Ind)Cl2]
Umicore Grubbs Catalyst M20 SIPr
1307233-23-3(SIPr)Ru(PPh3)(Ind)Cl2
Umicore Grubbs Catalyst M1
250220-36-1Ru(PCy3)2(Ind)Cl2
PEPPSI IPr
905459-27-0[(IPr)Pd(3-Cl-py)Cl2]
Umicore CX42
627878-09-5[(SIPr)PdCl2]2
[Rh(C7H15COO)2]2
73482-96-9[Rh(C7H15COO)2]2
Chiralyst P618
12354-85-7[Rh(C5Me5)Cl2]2
Chiralyst P442
29998-99-0[Rh(OAc)2]2 x n H2O
Rh(OAc)3 solution
42204-14-8Rh(OAc)3 solution
Umicore CX93
72287-26-4[Pd(dppf)Cl2]
Umicore CX96
95408-45-0[Pd(dtbpf)Cl2]
Chiralyst P1271
666826-16-0[Ir(cod)2]BArF
Umicore HS302
68585-32-0Pt(cs)cs
RuCl3 x n H2O
14898-67-0RuCl3 x n H2O
Pd-Tetrakis
14221-01-3[Pd(PPh3)4]
[(PPh3)AuCl]
14243-64-2[(PPh3)AuCl]
Umicore CX32
884879-24-7(SIPr)Pd(cinnamyl)Cl
Umicore CX31
884879-23-6[(IPr)Pd(cinnamyl)Cl]
Umicore CX81
34409-44-4Pd(P(tBu)2Ph)2Cl2
CPCOCO
12078-25-0Co(CO)2Cp
Umicore Grubbs Catalyst M32h SIPr
1416427-12-7
Umicore CX51
478019-87-3[(IPr)Pd(vs)]
[Ir(acac)3]
15635-87-7[Ir(acac)3]
Chiralyst Ru1254
1021494-93-8Ru(SL-W001-1)(C7H11)I
Chiralyst P294
32354-50-0Rh(nbd)(acac)
Umicore HS206
68478-92-2Pt(vs)cs
Nishimura's catalyst
39373-27-8 / 52785-06-5Rh2O3 / PtO2 x n H2O
Pt(TAA) solution
127733-97-5[Pt(NH3)4](OAc)2 solution
Umicore HS156
60134-75-0[Pt(cyclohexene)CI2]2
Umicore CX52
441018-46-8[(IMes)Pd(vs)]
Umicore CX54
1004291-85-3[(SIMes)Pd(vs)]
Umicore CX61
252062-59-2Pd(vs)c
Umicore Hoveyda-Grubbs Catalyst M71 SIPr
1212008-99-5
Chiralyst Ru636
192139-92-7Ru[(R,R)-TsDPEN](p-cymene)Cl
Chiralyst Rh756
56977-92-5[Rh[(R,R)-DIPAMP](cod)]BF4
[Ru(C5Me5)Cl2]n
96503-27-4[Ru(C5Me5)Cl2]n
Ru HYDRIDO
16971-33-8Ru(PPh3)3(CO)(H)Cl
Ru(nbd)Cl2
48107-17-1Ru(nbd)Cl2
[Ru(SL-J009-2)(C7H11)(N-AcCN)]BF4
Umicore Grubbs Catalyst M11
894423-99-5Ru(iBu-phobane)2(Ind)Cl2
[Pd(C6H5CN)2Cl2]
14220-64-5[Pd(C6H5CN)2Cl2]
Chiralyst Ru914
916197-27-8Ru[(R)-Xyl-MeO-BIPHEP](OAc)2
[Rh(SL-T002-1)(cod)]BF4
Chiralyst Ru637
192139-90-5Ru[(S,S)-TsDPEN](p-cymene)Cl
Ru(PPh3)3Cl2
15529-49-4Ru(PPh3)3Cl2
ROPAC
25470-96-6Rh(PPh3)(CO)(acac)
Umicore DeRu33
12215-07-5Ru(C6H8)(C6H6)
Chiralyst P406
145271-55-2[Ru(CH3CN)3(C7H11)]BF4
Chiralyst P379
122260-79-1[Ru(C7H11)(C7H14)]BF4
Umicore DeRu28
85908-78-7Ru(C7H11)2
Chiralyst P320
12289-94-0Ru(cod)(methylallyl)2
Umicore DeRu21
857678-47-8[Ru(MeCOCH(CH2)Me)2]
Umicore CX92
59831-02-6[Pd(dppp)Cl2]
[Pd(cod)Cl2]
12107-56-1[Pd(cod)Cl2]
Umicore CX72
29934-17-6[Pd(PCy3)2Cl2]
Umicore CX73
13965-03-2[Pd(PPh3)2Cl2]
CARAC
14874-82-9Rh(CO)2(acac)
Rh HYDRIDO
17185-29-4Rh(PPh3)3(CO)H
[Pd(allyl)Cl]2
12012-95-2[Pd(allyl)Cl]2
Umicore CX23
478980-01-7(SIPr)Pd(allyl)Cl
Umicore CX22
478980-04-0[(IMes)Pd(allyl)Cl]
Fu catalyst
53199-31-8[Pd(P(tBu3))2]
Umicore CX84
887919-35-9[Pd(amphos)2Cl2]
Elyst Ir75 0480
12030-49-8IrO2 on oxidic support
Chiralyst Rh1351
827596-70-3[Rh(SL-M004-1)(cod)]BF4
Chiralyst Rh640
219944-99-7Rh[(S,S)-TsDPEN](C5Me5)Cl
Chiralyst Ru762
952040-51-6Ru[(R)-2-Furyl-MeO-BIPHEP](OAc)2
Chiralyst Ru1267
1021494-98-3[Ru(SL-W008-1)(C7H11)(N-AcCN)]BF4
Chiralyst Ru1255
1021494-95-0[Ru(SL-W001-1)(C7H11)(N-AcCN)]BF4
Chiralyst Ru1251
194497-14-8Ru[(R)-3,5-t-Bu-MeO-BIPHEP](OAc)2
Chiralyst Ru843
261948-85-0Ru[(S)-BINAP](OAc)2
Chiralyst Ru842
325146-81-4Ru[(R)-BINAP](OAc)2
Chiralyst Ru803
134527-17-6Ru[(S)-MeO-BIPHEP](OAc)2
Chiralyst Ru802
133519-04-7Ru[(R)-MeO-BIPHEP](OAc)2
Chiralyst Ru1011
942042-52-6Ru(SL-T001-1)(C7H11)I
Chiralyst Ru1012
942042-53-7Ru(SL-T001-2)(C7H11)I
Chiralyst Ru928
126251-92-1[RuCl(benzene)(S)-BINAP)]Cl
Chiralyst Ru930
130004-33-0[RuCl(p-cymene)(S)-BINAP)]Cl
Chiralyst Rh639
223392-99-2Rh[(R,R)-TsDPEN](C5Me5)Cl
Chiralyst Rh1228
673458-88-3[Rh(SL-W001-1)(cod)]BF4
Chiralyst Rh840
673458-86-1[Rh(SL-J002-1)(cod)]BF4
Chiralyst P1163
33040-12-9[Ir(C5Me5)I2]2
Chiralyst P797
12354-84-6[Ir(C5Me5)Cl2]2
Umicore HS125
15604-36-1[Pt(PPh3)2Cl2]
Umicore HS152
12080-32-9[Pt(cod)Cl2]
CIA solution
16941-92-7H2[IrCl6] solution
Ru(cod)(C5Me5)Cl
92390-26-6Ru(cod)(C5Me5)Cl
Umicore DeRu37
15243-33-1Ru3(CO)12
Chiralyst P327
133519-03-6Ru(cod)(OAc)2
Chiralyst P889
93582-31-1[Ru(cod)(CF3CO2)2]2 x n H2O
[Ru(C6Me6)CI2]2
67421-02-7[Ru(C6Me6)CI2]2
Chiralyst P500
37366-09-9[Ru(C6H6)CI2]2
Chiralyst P612
52462-29-0[Ru(p-cymene)CI2]2
Chiralyst P978
90614-07-6[Ru(p-cymene)I2]2
[Ru(acac)3]
14284-93-6[Ru(acac)3]
Ru(OAc)3 solution
55466-76-7Ru(OAc)3 solution
Chiralyst P1182
404573-66-6[Rh(cod)2]BArF
Chiralyst P374
36620-11-8[Rh(nbd)2]BF4
Chiralyst P461
12257-42-0[Rh(nbd)Cl]2
Chiralyst P407
35138-22-8[Rh(cod)2]BF4
Chiralyst P493
12092-47-6[Rh(cod)Cl]2
Chiralyst P310
12245-39-5Rh(cod)(acac)
[Rh(acac)3]
14284-92-5[Rh(acac)3]
Umicore Grubbs Catalyst M51
1031262-71-1
Umicore Grubbs Catalyst M22
1255536-61-8[(SIMes)Ru(P(OiPr)3)(Ind)Cl2]
Umicore Grubbs Catalyst M20
340810-50-6[(SIMes)Ru(PPh3)(Ind)Cl2]
Umicore Grubbs Catalyst M2
536724-67-1(SIMes)Ru(PCy3)(Ind)Cl2
PEPPSI SIPr
927706-57-8(SIPr)Pd(3-Cl-py)Cl2
Umicore CX41
444910-17-2[(IPr)PdCl2]2
Umicore CX21
478980-03-9[(IPr)Pd(allyl)CI]
Chiralyst Rh1119
673458-82-7[Rh(SL-M001-1)(cod)]BF4
Umicore Hoveyda-Grubbs Catalyst M73 SIPr
1212009-05-6
Umicore Hoveyda-Grubbs Catalyst M73
1025728-57-7
[(IPr)AgCl]
873297-19-9[(IPr)AgCl]
[(IPr)AuCl]
852445-83-1[(IPr)AuCl]
[(tht)AuCl]
39929-21-0[(tht)AuCl]
[Ru(mesitylene)CI2]2
52462-31-4[Ru(mesitylene)CI2]2
Umicore HS426
873311-51-4(SIPr)Pt(vs)
Umicore HS203
68478-92-2Pt(vs)ipa
Umicore HS202
68478-92-2Pt(vs)x
Umicore HS220
68478-92-2Pt(vs)c type A
Umicore HS149
15170-57-7[Pt(acac)2]
CAA solution 38
16903-35-8H[AuCl4] solution
Ru(NO)(NO3)3 solution
34513-98-9Ru(NO)(NO3)3 solution
Ru(NO)(NO3)3
34513-98-9Ru(NO)(NO3)3
RuO2 x n H2O
32740-79-7RuO2 x n H2O
RuO2
12036-10-1RuO2
Ru Black
7440-18-8Ru
Rh nitrate solution
10139-58-9Rh(NO3)3 solution
Rh(NO3)3 x n H2O
13465-43-5Rh(NO3)3 x n H2O
RhCl3
10049-07-7RhCl3
RhCl3 solution
13569-65-8RhCl3 solution
Pd(TAS)
13601-06-4[Pd(NH3)4]SO4
Pd(TAC) solution
13815-17-3[Pd(NH3)4]Cl2 solution
Pd(TAN) solution type NH
13601-08-6[Pd(NH3)4](NO3)2 solution
[Pd(NH3)2(NO2)2] sol. in ammonia
[Pd(CH3CN)2Cl2]
14592-56-4[Pd(CH3CN)2Cl2]
Umicore CX74
40691-33-6[Pd(P(o-tol)3)2Cl2]
[Pd2(dba)3] x dba
51364-51-3[Pd2(dba)3] x dba
Umicore CX95
851232-71-8[Pd(dppf)Cl2] x (CH3)2CO
Umicore CX91
19978-61-1[Pd(dppe)Cl2]
Umicore CX94
95464-05-4[Pd(dppf)Cl2] x CH2Cl2
[Pd(cinnamyl)Cl]2
12131-44-1[Pd(cinnamyl)Cl]2
[Pd(OAc)2]3
3375-31-3[Pd(OAc)2]3
[Pd(acac)2]
14024-61-4[Pd(acac)2]
[Ir(coe)2Cl]2
12246-51-4[Ir(coe)2Cl]2
Umicore HS157
12112-67-3[Ir(cod)Cl]2
[Ir(cod)(acac)]
12154-84-6[Ir(cod)(acac)]
Na2[PtCl6] x n H2O
19583-77-8Na2[PtCl6] x n H2O
Pt EA solution low Cl
68133-90-4(HOCH2CH2NH3)2[Pt(OH)6] sol.
Pt EA solution
68133-90-4(HOCH2CH2NH3)2[Pt(OH)6] sol.
Pt(TAA) solution low Cl
127733-97-5[Pt(NH3)4](OAc)2 solution
Pt(TAN) solution
20634-12-2[Pt(NH3)4](NO3)2 solution
Pt(TAC) solution
13933-33-0[Pt(NH3)4]Cl2 solution
HPA
51850-20-5H2[Pt(OH)6]
Pt Black 32
7440-06-4Pt
Pd(DAC)
14323-43-4[Pd(NH3)2Cl2]
PdSO4 x n H2O
13444-98-9PdSO4 x n H2O
Pd nitrate solution type ACG
10102-05-3Pd(NO3)2 solution type ACG
Pd nitrate solution type H
10102-05-3Pd(NO3)2 solution type H
Pd(NO3)2 x n H2O
32916-07-7Pd(NO3)2 x n H2O
Na2[PdCl4] solution
13820-53-6Na2[PdCl4] solution
Pd(II)-chloride solution 20
16970-55-1H2[PdCl4] solution
Pd Black
7440-05-3Pd
K2[IrCl6]
16920-56-2K2[IrCl6]
IrCl4/IrCl3 x n H2O
207399-11-9IrCl4/IrCl3 x n H2O
Ir Black
7439-88-5Ir
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