Umicore CX32

Umicore CX32

Chlorophenylallyl[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]palladium(II)

CAS Number: 884879-24-7

Product class: Homogeneous Catalysts, M-C, Allyl Ligands, N-Heterocyclic Carbene Ligands, SIPr, M-P, Bidentate Ligands

Reaction type: Amination, Buchwald-Hartwig Aminaton, Cross Coupling Reactions with Arenes, Suzuki-Miyaura Coupling Reaction

Chemical properties

Chemical formula

C36H47N2ClPd

Empirical formula

(SIPr)Pd(cinnamyl)Cl

Molecular weight

649.65

Metal

Pd

Theoretical metal content

16

Physical state

crystalline

Color

pale yellow

Metal purity

99.95

Legal information

US 6 316 380, WO 2004 014550 and foreign equivalents apply.

Applications & references

Suzuki-Miyaura coupling reaction step in the total synthesis of GPRP52 agonist, a preventive and therapeutic agent for schizophrenia.

Reference: WO2010 0188874

Buchwald-Hartwig coupling reactions.

Reference: J. Am. Chem. Soc. 2006, 128, 4101 (DOI: 10.1021/ja057704z); Chem. Eur. J. 2006, 12, 5142 (DOI: 10.1002/chem.200600283)

Cyclopentannulation of diazabicycles.

Reference: Org. Lett. 2010, 12, 5422 (DOI:10.1021/ol050895q)

Palladium catalyzed anaerobic oxidation of secondary alcohols under mild reaction conditions.

Reference: J. Org. Chem. 2011, 76, 1390 (DOI: 10.1021/jo102385u)

Palladium catalyzed Buchwald-Hartwig- Reaction at room temperature.

Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)

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