Umicore CX31

Umicore CX31

Chlorophenylallyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]palladium (II)

CAS Number: 884879-23-6

Product class: Homogeneous Catalysts, M-C, Allyl Ligands, N-Heterocyclic Carbene Ligands, IPr, M-P, Bidentate Ligands

Reaction type: Amination, Buchwald-Hartwig Aminaton, Cross Coupling Reactions with Arenes, Suzuki-Miyaura Coupling Reaction

Chemical properties
Chemical formula

C35H45N2ClPd

Empirical formula

[(IPr)Pd(cinnamyl)Cl]

Molecular weight

647.63

Metal

Pd

Theoretical metal content

16

Physical state

crystalline

Color

pale yellow

Metal purity

99.95

Legal information

US 6 316 380, WO 2004 014550 and foreign equivalents apply.

Applications & references

Suzuki-Miyaura coupling reactions at low catalyst loadings.

Reference: J. Am. Chem. Soc. 2006, 128, 4101 (DOI: 10.1021/ja057704z); Chem. Eur. J. 2006, 12, 5142 (DOI: 10.1002/chem.200600283)

Buchwald-Hartwig coupling reactions. 

Reference: J. Am. Chem. Soc. 2006, 128, 4101 (DOI: 10.1021/ja057704z)

Suzuki-Miyaura coupling reactions in water facilitated by non-ionic amphiphiles.

Reference: Org. Lett. 2008, 10, 13331 (DOI: 10.1021/ol702714y)

Palladium catalyzed anaerobic oxidation of secondary alcohols under mild reaction conditions.

Reference: J. Org. Chem. 2011, 76, 1390 (DOI: 10.1021/jo102385u)

Suzuki-Miyaura cross coupling of aryl chlorides at very low Palladium catalyst loadings.

Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)

Palladium catalyzed Buchwald-Hartwig- Reaction at room temperature.

Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)

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