Umicore Grubbs Catalyst M204

Umicore Grubbs Catalyst M204

Chemical properties

Chemical formula

C46H65Cl2N2PRu

Empirical formula

(SIMes)Ru(PCy3)(benzylidene)Cl2

Molecular weight

848.97

Metal

Ru

Theoretical metal content

12

Physical state

powder

Color

orange-brown

Metal purity

99.95

Applications & references

Asymmetric synthesis of new cyclic fluorinated amino-acids

Reference: European Journal of Organic Chemistry, March 2018

 

Photoinduced strain-assisted synthesis of a stiff-stilbene polymer by ring-opening metathesis polymerization.

Reference: Chem. Eur. J. 2020 (10.1002/chem.20200418)

 

Facile synthetic route to [3.n]thiacyclophanes via ring-closing metathesis.

Reference: Eur. J. Org. Chem. 2020 (10.1002/ejoc.202000697)

 

RCM-Based Total Synthesis of the Antibiotic Disciformycin B.

Reference: Angew. Chem. Int. Ed. 2020 (doi.org/10.1002/anie.202004589)

 

Sequential two-fold Claisen Rearrangement, One-pot Ring Closing Metathesis and Cross-metathesis as a Route to Substituted Benzo[b]azepine-2-one, Benzo[b]azepine and Benzo[b]oxepine Derivatives.

Reference: Helv Chem Acta 2020 ASAP (doi.org/10.1002/hlca.202000216)

 

Sequence-regulated vinyl polymers via iterative atom transfer radical additions and acyclic diene metathesis polymerization.

Reference: Polym Chem 2020 ASAP (doi.org/10.1039/D0PY01564D)

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