Umicore Grubbs Catalyst M204

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(benzylidene)(tricyclohexylphosphine)ruthenium(II)

CAS Number: 246047-72-3

Metal:

Ruthenium

Product class:

Application:

Reaction type:

Chemical properties

Chemical formula

C₄₆H₆₅Cl₂N₂PRu

Empirical formula

(SIMes)Ru(PCy₃)(benzylidene)Cl₂

Molecular weight

848.97

Metal

Theoretical metal content

Physical state

powder

Color

orange-brown

Metal purity

99.95

Applications & references

Asymmetric synthesis of new cyclic fluorinated amino-acids

Reference: European Journal of Organic Chemistry, March 2018

Photoinduced strain-assisted synthesis of a stiff-stilbene polymer by ring-opening metathesis polymerization.

Reference: Chem. Eur. J. 2020 (10.1002/chem.20200418)

Facile synthetic route to [3.n]thiacyclophanes via ring-closing metathesis.

Reference: Eur. J. Org. Chem. 2020 (10.1002/ejoc.202000697)

RCM-Based Total Synthesis of the Antibiotic Disciformycin B.

Reference: Angew. Chem. Int. Ed. 2020 (doi.org/10.1002/anie.202004589)

Sequential two-fold Claisen Rearrangement, One-pot Ring Closing Metathesis and Cross-metathesis as a Route to Substituted Benzo[b]azepine-2-one, Benzo[b]azepine and Benzo[b]oxepine Derivatives.

Reference: Helv Chem Acta 2020 ASAP (doi.org/10.1002/hlca.202000216)

Sequence-regulated vinyl polymers via iterative atom transfer radical additions and acyclic diene metathesis polymerization.

Reference: Polym Chem 2020 ASAP (doi.org/10.1039/D0PY01564D)

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Get in touch

Your contact person

Xiaofang Bi

T: +86 (21) 2411 6870

Phil Chalabi

T: +1 (918) 266 4826

Horiguchi Yoshiaki

T: +81 (3) 6685 3069

Chinmay Pandya

T: +91 (22) 6627 5656

Heidi Heuser

T: +49 (6181) 59 2413

Heidi Heuser

T: +49 (6181) 59 2413

Please order your research quantities at Merck / MilliporeSigma

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Umicore Grubbs Catalyst M204

Umicore Grubbs Catalyst M204

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(benzylidene)(tricyclohexylphosphine)ruthenium(II)

Chemical properties

Applications & references

Asymmetric synthesis of new cyclic fluorinated amino-acids

Photoinduced strain-assisted synthesis of a stiff-stilbene polymer by ring-opening metathesis polymerization.

Facile synthetic route to [3.n]thiacyclophanes via ring-closing metathesis.

RCM-Based Total Synthesis of the Antibiotic Disciformycin B.

Sequential two-fold Claisen Rearrangement, One-pot Ring Closing Metathesis and Cross-metathesis as a Route to Substituted Benzo[b]azepine-2-one, Benzo[b]azepine and Benzo[b]oxepine Derivatives.

Sequence-regulated vinyl polymers via iterative atom transfer radical additions and acyclic diene metathesis polymerization.

Request a quote or MSDS

Your contact person

Xiaofang Bi

Phil Chalabi

Horiguchi Yoshiaki

Chinmay Pandya

Heidi Heuser

Heidi Heuser

Please order your research quantities at Merck / MilliporeSigma

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