Umicore Grubbs Catalyst M202
Umicore Grubbs Catalyst M202
[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II)
CAS Number: 536724-67-1
Metal:
Product class:
- Homogeneous CatalystsGrubbs Catalyst® 2nd Generation
- Homogeneous CatalystsM-CN-Heterocyclic Carbene LigandsSIMes
- Homogeneous CatalystsM-PPhosphorus Ligands - Achiral
Application:
Reaction type:
Applications & references
Cross metathesis of terpenoids.
Reference: WO2012 004414
Preparation of α,ω-diacids starting from methyl oleate via self metathesis.
Reference: WO2010 020368
Cross metathesis of (E)-ethyl 2-isopropylpenta-2,4-dienoate for the synthesis of pharmaceutical active compounds , in particular rennin inhibitors.
Reference: WO2008 155338
Ring closing metathesis in the total synthesis of desoxyepothilone derivatives, which inhibit the growth of tumor cells.
Reference: WO2006 111491
Challenging ring closing metathesis.
Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)
Enyne cycloisomerization.
Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)
Enyne ring closing metathesis.
Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)
Cross metathesis of functionalized alkenes.
Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)
Ring rearrangement metathesis.
Reference: Eur. J. Org. Chem. 2010, 937 (DOI: 10.1002/ejoc.200901316)
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