Umicore Grubbs Catalyst M202

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II)

CAS Number: 536724-67-1

Product class:

Reaction type:

Chemical properties

Chemical formula

C₅₄H₆₉N₂Cl₂PRu

Empirical formula

(SIMes)Ru(PCy₃)(Ind)Cl₂

Molecular weight

949.10

Metal

Theoretical metal content

Physical state

powder

Color

red brown

Metal purity

99.95

Legal information

WO 2000 15339, US 10 873 026 and foreign equivalents apply. For use in pharmaceutical applications.

Applications & references

Cross metathesis of terpenoids.

Reference: WO2012 004414

Preparation of α,ω-diacids starting from methyl oleate via self metathesis.

Reference: WO2010 020368

Cross metathesis of (E)-ethyl 2-isopropylpenta-2,4-dienoate for the synthesis of pharmaceutical active compounds , in particular rennin inhibitors.

Reference: WO2008 155338

Ring closing metathesis in the total synthesis of desoxyepothilone derivatives, which inhibit the growth of tumor cells.

Reference: WO2006 111491

Challenging ring closing metathesis.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

Enyne cycloisomerization.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

Enyne ring closing metathesis.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

Cross metathesis of functionalized alkenes.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

Ring rearrangement metathesis.

Reference: Eur. J. Org. Chem. 2010, 937 (DOI: 10.1002/ejoc.200901316)

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Your contact person

Chinmay Pandya

T: +91 (22) 6627 5656

Xiaofang Bi

T: +86 (21) 2411 6870

Heidi Heuser

T: +49 (6181) 59 2413

Horiguchi Yoshiaki

T: +81 (3) 6685 3069

Phil Chalabi

T: +1 (918) 266 4826

Heidi Heuser

T: +49 (6181) 59 2413

Please order your research quantities at Merck / MilliporeSigma

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Umicore Grubbs Catalyst M202

Umicore Grubbs Catalyst M202

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II)

Chemical properties

Legal information

Applications & references

Cross metathesis of terpenoids.

Preparation of α,ω-diacids starting from methyl oleate via self metathesis.

Cross metathesis of (E)-ethyl 2-isopropylpenta-2,4-dienoate for the synthesis of pharmaceutical active compounds , in particular rennin inhibitors.

Ring closing metathesis in the total synthesis of desoxyepothilone derivatives, which inhibit the growth of tumor cells.

Challenging ring closing metathesis.

Enyne cycloisomerization.

Enyne ring closing metathesis.

Cross metathesis of functionalized alkenes.

Ring rearrangement metathesis.

Request a quote or MSDS

Your contact person

Chinmay Pandya

Xiaofang Bi

Heidi Heuser

Horiguchi Yoshiaki

Phil Chalabi

Heidi Heuser

Please order your research quantities at Merck / MilliporeSigma

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