Umicore Grubbs Catalyst M102

Umicore Grubbs Catalyst M102


CAS Number: 172222-30-9

Product class: M-P, Homogeneous Catalysts, M-C, Grubbs Catalyst® 1st Generation, Carbene Ligands, Phosphorus Ligands - Achiral

Reaction type: Alkene Metathesis, Acyclic Diene Metathesis, Cross Metathesis, Ring Arrangement Metathesis , Ring Closing Metathesis, Ring Opening Metathesis Polymerization, Self Metathesis

Chemical properties

Chemical formula


Empirical formula


Molecular weight




Theoretical metal content


Physical state




Metal purity


Applications & references

Formal Synthesis of (-)-Haliclonin A: Stereoselective Construction of an Azabicyclo[3.3.1]nonane Ring System by a Tandem Radical Reaction.

Reference: Org. Lett. 2020, 22, 13, 5046–5050


Formylation of a metathesis-derived ansa[4]-ferrocene: a simple route to anticancer organometallics.

Reference: Dalton Trans. 2020, (


Aerogels for the separation of asphalt-containing oil–water mixtures and the effect of asphalt stabilizer.

Reference: RSC Adv. 2020,10, 24840-24846


Asymmetric total synthesis of the naturally occurring antibiotic Anthracimycin

Reference: Org. Lett. 2020, 22, 14, 5550–5554


Sequential two-fold Claisen Rearrangement, One-pot Ring Closing Metathesis and Cross-metathesis as a Route to Substituted Benzo[b]azepine-2-one, Benzo[b]azepine and Benzo[b]oxepine Derivatives.

Reference: Helv Chem Acta 2020 ASAP (

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