Umicore Grubbs Catalyst M102

Umicore Grubbs Catalyst M102

Chemical properties

Chemical formula

C43H72Cl2P2Ru

Empirical formula

Ru(PCy3)2(benzylidene)Cl2

Molecular weight

822.96

Metal

Ru

Theoretical metal content

12

Physical state

powder

Color

purple

Metal purity

99.95

Applications & references

Formal Synthesis of (-)-Haliclonin A: Stereoselective Construction of an Azabicyclo[3.3.1]nonane Ring System by a Tandem Radical Reaction.

Reference: Org. Lett. 2020, 22, 13, 5046–5050

 

Formylation of a metathesis-derived ansa[4]-ferrocene: a simple route to anticancer organometallics.

Reference: Dalton Trans. 2020, (doi.org/10.1039/D0DT01975E)

 

Aerogels for the separation of asphalt-containing oil–water mixtures and the effect of asphalt stabilizer.

Reference: RSC Adv. 2020,10, 24840-24846

 

Asymmetric total synthesis of the naturally occurring antibiotic Anthracimycin

Reference: Org. Lett. 2020, 22, 14, 5550–5554

 

Sequential two-fold Claisen Rearrangement, One-pot Ring Closing Metathesis and Cross-metathesis as a Route to Substituted Benzo[b]azepine-2-one, Benzo[b]azepine and Benzo[b]oxepine Derivatives.

Reference: Helv Chem Acta 2020 ASAP (doi.org/10.1002/hlca.202000216)