Umicore Grubbs Catalyst M102

Umicore Grubbs Catalyst M102

Dichloro(benzylidene)bis(tricyclohexylphosphine)ruthenium(II)

CAS Number: 172222-30-9

Product class: M-P, Homogeneous Catalysts, M-C, Grubbs Catalyst® 1st Generation, Carbene Ligands, Phosphorus Ligands - Achiral

Reaction type: Alkene Metathesis, Acyclic Diene Metathesis, Cross Metathesis, Ring Arrangement Metathesis , Ring Closing Metathesis, Ring Opening Metathesis Polymerization, Self Metathesis

Chemical properties

Chemical formula

C43H72Cl2P2Ru

Empirical formula

Ru(PCy3)2(benzylidene)Cl2

Molecular weight

822.96

Metal

Ru

Theoretical metal content

12

Physical state

powder

Color

purple

Metal purity

99.95

Applications & references

Formal Synthesis of (-)-Haliclonin A: Stereoselective Construction of an Azabicyclo[3.3.1]nonane Ring System by a Tandem Radical Reaction.

Reference: Org. Lett. 2020, 22, 13, 5046–5050

 

Formylation of a metathesis-derived ansa[4]-ferrocene: a simple route to anticancer organometallics.

Reference: Dalton Trans. 2020, (doi.org/10.1039/D0DT01975E)

 

Aerogels for the separation of asphalt-containing oil–water mixtures and the effect of asphalt stabilizer.

Reference: RSC Adv. 2020,10, 24840-24846

 

Asymmetric total synthesis of the naturally occurring antibiotic Anthracimycin

Reference: Org. Lett. 2020, 22, 14, 5550–5554

 

Sequential two-fold Claisen Rearrangement, One-pot Ring Closing Metathesis and Cross-metathesis as a Route to Substituted Benzo[b]azepine-2-one, Benzo[b]azepine and Benzo[b]oxepine Derivatives.

Reference: Helv Chem Acta 2020 ASAP (doi.org/10.1002/hlca.202000216)

Request a quote or MSDS

Your contact person

Chinmay Pandya

T: +91 (22) 6627 5656
Email

Horiguchi Yoshiaki

T: +81 (3) 6685 3069
Email

Phil Chalabi

T: +1 (918) 266 4826
Email

Heidi Heuser

T: +49 (6181) 59 2413
Email

Xiaofang Bi

T: +86 (21) 2411 6870
Email

Heidi Heuser

T: +49 (6181) 59 2413
Email

Please order your research quantities at Merck / MilliporeSigma

×

      Umicore uses certain monitoring and tracking technologies such as cookies. These technologies are used in order to maintain, provide and improve our services on an ongoing basis, and in order to provide our web visitors with a better experience.

      By clicking on the "Accept all" button you agree to the use of these cookies while using the website. For further information regarding how we use cookies and other tracking technologies, please see section 11 of our website privacy notice

          Necessary cookies are essential and help you navigate our website. This helps to support security and basic functionality and are necessary for the proper operation of our website, so if you block these cookies we cannot guarantee your use or the security during your visit.

          Cookies that help us to understand the behaviour of users of our website. This allows us to continuously improve our website to provide the best information in support of our project aims. These cookies also help us understand the effectiveness of our website. For instance these cookies tell us which pages visitors go to most often and if they get error messages from web pages.

          Cookies that deliver content to you based on your interests, which are assumed from your browsing history. Most Targeting Cookies track users via their IP address and, thus, may collect some Personal Data. Personal Data collected by Targeting Cookies may be shared with third parties, such as advertisers.