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Business unit / dept.: Precious Metals Chemistry

Umicore CX96

Umicore CX96

Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II)

CAS Number: 95408-45-0

Chemical properties

Chemical formula

C26H44Cl2FeP2Pd

Empirical formula

[Pd(dtbpf)Cl2]

Molecular weight

651.75

Metal

Pd

Theoretical metal content

16

Physical state

crystalline

Color

red

Metal purity

99.95

Your contact person

Yukari Nakada

T: +81 90 9018 6731
Email

Chinmay Pandya

T: +91 9867662944
Email

Don Zeng

T: +1 (714) 777 3737
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Heidi Heuser

T: +49 6181 706 4787
Email

Ula Rao

T: +86 (21) 2411 6843
Email

Heidi Heuser

T: +49 6181 706 4787
Email

Applications & references

Description

Reductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.

Reference: Org. Proc. Res. Dev. 2007, 11, 39. (DOI: 10.1021/op060193w)

 

Total synthesis of diacyl glycerolacyltransferase-1 (DGAT-1) inhibitor including an ambient temperature Suzuki−Miyaura coupling reaction. DGAT-1 is one of two isoforms which catalyze the final and committed step of triglyceride biosynthesis. This compound could play a decisive role in the development of obesity and insulin resistance. 

Reference: Org. Proc. Res. Dev. 2010, 14, 417 (DOI: 10.1021/op900310v)

 

High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl bromides.

Reference: J. Org. Chem. 2010, 75, 6998. (DOI: 10.1021/jo101433g)

 

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