Umicore CX93

Umicore CX93

Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II)

CAS Number: 72287-26-4

Product class: M-P, Homogeneous Catalysts, Bidentate Ligands, Ferrocenyl Ligands - Achiral

Reaction type: Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, C-H Activation, Carbonylation, Negishi Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction, Oxidation

Chemical properties

Chemical formula

C34H28Cl2FeP2Pd

Empirical formula

[Pd(dppf)Cl2]

Molecular weight

731.71

Metal

Pd

Theoretical metal content

14

Physical state

crystalline

Color

red

Metal purity

99.95

Applications & references

Reductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.

Reference: Org. Proc. Res. Dev. 2007, 11, 39. (DOI: 10.1021/op060193w), Synthesis 1996, 470 (DOI: 10.1055/s-1996-4246)

 

High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl bromides.

Reference: J. Org. Chem. 2010, 75, 6998. (DOI: 10.1021/jo101433g)

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