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Business unit / dept.: Precious Metals Chemistry

Umicore CX32

Umicore CX32

Chlorophenylallyl[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]palladium(II)

CAS Number: 884879-24-7

Chemical properties

Chemical formula

C36H47N2ClPd

Empirical formula

(SIPr)Pd(cinnamyl)Cl

Molecular weight

649.65

Metal

Pd

Theoretical metal content

16

Physical state

crystalline

Color

pale yellow

Metal purity

99.95

Your contact person

Yukari Nakada

T: +81 90 9018 6731
Email

Celine Jung

T: +1 918-266-4911
Email

Heidi Heuser

T: +49 6181 706 4787
Email

Coco Wang

T: +81 (21) 2411 6843
Email

Chinmay Pandya

T: +91 9867662944
Email

Heidi Heuser

T: +49 6181 706 4787
Email

Please order your research quantities at Merck / MilliporeSigma

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Applications & references

Description

Suzuki-Miyaura coupling reaction step in the total synthesis of GPRP52 agonist, a preventive and therapeutic agent for schizophrenia.

Reference: WO2010 0188874

 

Buchwald-Hartwig coupling reactions.

Reference: J. Am. Chem. Soc. 2006, 128, 4101 (DOI: 10.1021/ja057704z); Chem. Eur. J. 2006, 12, 5142 (DOI: 10.1002/chem.200600283)

 

Cyclopentannulation of diazabicycles.

Reference: Org. Lett. 2010, 12, 5422 (DOI:10.1021/ol050895q)

 

Palladium catalyzed anaerobic oxidation of secondary alcohols under mild reaction conditions.

Reference: J. Org. Chem. 2011, 76, 1390 (DOI: 10.1021/jo102385u)

 

Palladium catalyzed Buchwald-Hartwig- Reaction at room temperature.

Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)

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