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Umicore CX32

Umicore CX32

Chemical properties

Chemical formula

C36H47N2ClPd

Empirical formula

(SIPr)Pd(cinnamyl)Cl

Molecular weight

649.65

Metal

Pd

Theoretical metal content

16

Physical state

crystalline

Color

pale yellow

Metal purity

99.95

Applications & references

Description

Suzuki-Miyaura coupling reaction step in the total synthesis of GPRP52 agonist, a preventive and therapeutic agent for schizophrenia.

Reference: WO2010 0188874

 

Buchwald-Hartwig coupling reactions.

Reference: J. Am. Chem. Soc. 2006, 128, 4101 (DOI: 10.1021/ja057704z); Chem. Eur. J. 2006, 12, 5142 (DOI: 10.1002/chem.200600283)

 

Cyclopentannulation of diazabicycles.

Reference: Org. Lett. 2010, 12, 5422 (DOI:10.1021/ol050895q)

 

Palladium catalyzed anaerobic oxidation of secondary alcohols under mild reaction conditions.

Reference: J. Org. Chem. 2011, 76, 1390 (DOI: 10.1021/jo102385u)

 

Palladium catalyzed Buchwald-Hartwig- Reaction at room temperature.

Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)