Umicore CX231
Umicore CX231
Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](1-tert-butyl-1H-inden-1-yl)palladium(II)
CAS Number: 1779569-04-8
Please order your research quantities at Merck / MilliporeSigma
Applications & references
Description
Suzuki-Miyaura coupling reactions of various substrates using a weak base showing the significant outperformance of Umicore CX231 compared to Umicore CX31. The conversion of substrates with deactivating electron-donating groups and substituents in the ortho-positions is feasible.
Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)
Suzuki-Miyaura coupling reaction of both linear and cyclic alkyl trifluoroboronates salts and various aryl chlorides, including an example of a nitrogen-containing heterocycle.
Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)
Firstly reported Hiyama-Denmark reactions using aryl silanolates as nucleophiles as an alternative to Suzuki-Miyaura reactions.
Reference: Org. Lett. 2016, 18, 5784 (DOI: 10.1021/acs.orglett.6b02330)
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