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Business unit / dept.: Precious Metals Chemistry

Umicore CX93

Umicore CX93

Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II)

CAS Number: 72287-26-4

Chemical properties

Chemical formula

C34H28Cl2FeP2Pd

Empirical formula

[Pd(dppf)Cl2]

Molecular weight

731.71

Metal

Pd

Theoretical metal content

14

Physical state

crystalline

Color

red

Metal purity

99.95

Your contact person

Yukari Nakada

T: +81 90 9018 6731
Email

Heidi Heuser

T: +49 6181 706 4787
Email

Don Zeng

T: +1 (714) 777 3737
Email

Chinmay Pandya

T: +91 9867662944
Email

Heidi Heuser

T: +49 6181 706 4787
Email

Applications & references

Description

Reductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.

Reference: Org. Proc. Res. Dev. 2007, 11, 39. (DOI: 10.1021/op060193w), Synthesis 1996, 470 (DOI: 10.1055/s-1996-4246)

 

High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl bromides.

Reference: J. Org. Chem. 2010, 75, 6998. (DOI: 10.1021/jo101433g)

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