Skip to main content Skip to primary navigation

Umicore CX21

Umicore CX21

Allylchloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]palladium(II)

CAS Number: 478980-03-9

Chemical properties

Chemical formula

C30H41N2ClPd

Empirical formula

[(IPr)Pd(allyl)CI]

Molecular weight

571.54

Metal

Pd

Theoretical metal content

19

Physical state

crystalline

Metal purity

99.95

Your contact person

Heidi Heuser

T: +49 (6181) 59 2413
Email

Ula Rao

T: +86 (21) 2411 6843
Email

Yukari Nakada

T: +81 90 9018 6731
Email

Don Zeng

T: +1 (714) 777 3737
Email

Chinmay Pandya

T: +91 9867662944
Email

Heidi Heuser

T: +49 (6181) 59 2413
Email

Please order your research quantities at Merck / MilliporeSigma

Applications & references

Description

Palladium catalyzed anaerobic oxidation of secondary alcohols under mild reaction conditions.

Reference: J. Org. Chem. 2011, 76, 1390. (DOI: 10.1021/jo102385u)

 

One-pot oxidation / α-ketone arylation of secondary alcohols.

Reference: J. Org. Chem. 2011, 76, 1390. (DOI: 10.1021/jo102385u)

 

Palladium catalyzed Buchwald-Hartwig-Reaction at room temperature.

Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)

 

α-Arylation of propiophenone.

Reference: Org. Lett. 2002, 4, 4053 (DOI: 10.1021/ol026745m)

 

Intramolecular arylamination step in the total synthesis of cryptocarya alkaloids.

Reference: Synlett 2003, 12, 1871 (DOI: 10.1055/s-2003-41468)

 

Dehalogenation reaction.

Reference: J. Org. Chem. 2004, 69, 3173 (DOI: 10.1021/jo035834p)

 

Suzuki-Miyaura coupling reaction.

 

Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)

Related products

Pd(PEPPSI)(IPr)

905459-27-0[(IPr)Pd(3-Cl-py)Cl2]

Precious Metals Chemistry

PMC

Pd-Tetrakis

14221-01-3[Pd(PPh3)4]

Precious Metals Chemistry

PMC

Umicore CX122 - Pd(XPhos)G2

1310584-14-5Pd(XPhos)[2-(2'-amino-1,1'-biphenyl)]Cl

Precious Metals Chemistry

PMC

Pd(PEPPSI)(SIPr)

927706-57-8[(SIPr)Pd(3-Cl-py)Cl2]

Precious Metals Chemistry

PMC

Umicore CX84

887919-35-9[Pd(amphos)2Cl2]

Precious Metals Chemistry

PMC

[Pd(OAc)2]3

3375-31-3[Pd(OAc)2]3

Precious Metals Chemistry

PMC

Umicore CX41

444910-17-2[(IPr)PdCl2]2

Precious Metals Chemistry

PMC

Umicore CX73

13965-03-2[Pd(PPh3)2Cl2]

Precious Metals Chemistry

PMC

Umicore CX135 - Pd(tBuXPhos)G3

1447963-75-8Pd(tBuXPhos)[2-(2'-amino-1,1'-biphenyl)](Ms)

Precious Metals Chemistry

PMC

[Pd(allyl)Cl]2

12012-95-2[Pd(allyl)Cl]2

Precious Metals Chemistry

PMC

Umicore CX72

29934-17-6[Pd(PCy3)2Cl2]

Precious Metals Chemistry

PMC

Umicore CX133 - Pd(RuPhos)G3

1445085-77-7Pd(RuPhos)[2-(2'-amino-1,1'-biphenyl)](Ms)

Precious Metals Chemistry

PMC

Umicore CX96

95408-45-0[Pd(dtbpf)Cl2]

Precious Metals Chemistry

PMC

Umicore CX93

72287-26-4[Pd(dppf)Cl2]

Precious Metals Chemistry

PMC

Umicore CX22

478980-04-0[(IMes)Pd(allyl)Cl]

Precious Metals Chemistry

PMC

Umicore CX15

185812-86-6[PdBr[P(tBu3)]]2

Precious Metals Chemistry

PMC

Umicore CX23

478980-01-7(SIPr)Pd(allyl)Cl

Precious Metals Chemistry

PMC

Umicore CX42

627878-09-5[(SIPr)PdCl2]2

Precious Metals Chemistry

PMC

[Pd(cod)Cl2]

12107-56-1[Pd(cod)Cl2]

Precious Metals Chemistry

PMC

Umicore CX33

1380314-24-8[(IPr*)Pd(cinnamyl)Cl]

Precious Metals Chemistry

PMC

Umicore CX32

884879-24-7(SIPr)Pd(cinnamyl)Cl

Precious Metals Chemistry

PMC

Umicore CX121 - Pd(SPhos)G2

1375325-64-6Pd(SPhos)[2-(2'-amino-1,1'-biphenyl)]Cl

Precious Metals Chemistry

PMC

Umicore CX62

1708984-17-1[Pd(dippf)(vs)tol]

Precious Metals Chemistry

PMC

Umicore CX76

59840-38-9[Pd(PCy3)2(OAc)2]

Precious Metals Chemistry

PMC

Umicore CX132 - Pd(XPhos)G3

1445085-55-1Pd(XPhos)[2-(2'-amino-1,1'-biphenyl)](Ms)

Precious Metals Chemistry

PMC

Umicore CX234

[(IPent)Pd(1-tBu-Ind)Cl]

Precious Metals Chemistry

PMC

Umicore CX123 - Pd(RuPhos)G2

1375325-68-0Pd(RuPhos)[2-(2'-amino-1,1'-biphenyl)]Cl

Precious Metals Chemistry

PMC

Umicore CX231

1779569-04-8[(IPr)Pd(1-tBu-Ind)Cl]

Precious Metals Chemistry

PMC

Umicore CX98

205319-06-8[Pd(DPEphos)Cl2]

Precious Metals Chemistry

PMC

Umicore CX136 - Pd(Xantphos)G3

1445085-97-1Pd(Xantphos)[2-(2'-amino-1,1'-biphenyl)](Ms)

Precious Metals Chemistry

PMC

Umicore CX131 - Pd(SPhos)G3

1445085-82-4Pd(SPhos)[2-(2'-amino-1,1'-biphenyl)](Ms)

Precious Metals Chemistry

PMC

Umicore CX31

884879-23-6[(IPr)Pd(cinnamyl)Cl]

Precious Metals Chemistry

PMC

Pd(PEPPSI)(IPent)

1158652-41-5[(IPent)Pd(3-Cl-py)Cl2]

Precious Metals Chemistry

PMC

Umicore CX201

1779569-15-1[Pd(1-tBu-Ind)(P(tBu)3)Cl]

Precious Metals Chemistry

PMC

Umicore CX51

478019-87-3[(IPr)Pd(vs)]

Precious Metals Chemistry

PMC

[Pd2(dba)3] x dba

51364-51-3[Pd2(dba)3] x dba

Precious Metals Chemistry

PMC

[Pd(C6H5CN)2Cl2]

14220-64-5[Pd(C6H5CN)2Cl2]

Precious Metals Chemistry

PMC

Umicore CX94

95464-05-4[Pd(dppf)Cl2] x CH2Cl2

Precious Metals Chemistry

PMC

Umicore CX52

441018-46-8[(IMes)Pd(vs)]

Precious Metals Chemistry

PMC

[Pd(cinnamyl)Cl]2

12131-44-1[Pd(cinnamyl)Cl]2

Precious Metals Chemistry

PMC

[Pd(acac)2]

14024-61-4[Pd(acac)2]

Precious Metals Chemistry

PMC

Umicore CX95

851232-71-8[Pd(dppf)Cl2] x (CH3)2CO

Precious Metals Chemistry

PMC

Umicore CX74

40691-33-6[Pd(P(o-tol)3)2Cl2]

Precious Metals Chemistry

PMC

Umicore CX97

205319-10-4[Pd(Xantphos)Cl2]

Precious Metals Chemistry

PMC

Umicore CX85

294673-79-3Pd(P(tBu)Ph2)2Cl2

Precious Metals Chemistry

PMC

Umicore CX512

2412537-46-1Pd(joYPhos)(cinnamyl)Cl

Precious Metals Chemistry

PMC

Umicore CX16

166445-62-1[PdI[P(tBu)3]]2

Precious Metals Chemistry

PMC

Umicore CX304

2789690-71-5Pd(cataCXium® A)(1-tBu-Ind)Cl

Precious Metals Chemistry

PMC

Umicore CX303

2703751-81-7Pd(cataCXium® A)(allyl)Cl

Precious Metals Chemistry

PMC

Umicore CX302

2789690-49-7Pd(cataCXium® A)(vs)

Precious Metals Chemistry

PMC

Umicore CX401 - Pd(PAd3)G3

2252175-57-6[Pd(PAd3)[2-(2'-amino-1,1'-biphenyl)](Ms)]

Precious Metals Chemistry

PMC

Umicore CX402

2866370-67-2Pd(PAd3)(1-tBu-Ind)Cl

Precious Metals Chemistry

PMC

Umicore CX222

1779569-06-0Pd(XPhos)(1-tBu-Ind)Cl

Precious Metals Chemistry

PMC

Umicore CX221

1779569-07-1Pd(SPhos)(1-tBu-Ind)Cl

Precious Metals Chemistry

PMC