Umicore CX97
Umicore CX97
Dichloro(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)palladium(II)
CAS Number: 205319-10-4
Applications & references
Description
Efficient oxidative carboxylation of benzylic C-H bonds via nondirected C(sp³)-H activation forming substituted 2-phenylacetic acid esters and derivatives starting from inexpensive, commercially available starting materials.
Reference: J. Am. Chem. Soc. 2012, 134, 9902 (10.1021/ja3036459)
High yielding palladium catalyzed esterification of aryl halides using aryl formates without using external carbon monoxide.
Reference: Chem. Comm. 2012, 48, 8012 (DOI: 10.1039/C2CC33944G)
Palladium catalyzed carbonylation of allyl amines via C-N bond activation yielding β,γ-unsaturated amides under moderately mild reaction conditions.
Reference: RSC Adv. 2014, 4, 64235 (10.1039/c4ra13939a)
Related products
Pd-Tetrakis
14221-01-3[Pd(PPh3)4]
Precious Metals Chemistry
PMC
[Pd(OAc)2]3
3375-31-3[Pd(OAc)2]3
Precious Metals Chemistry
PMC
Umicore CX73
13965-03-2[Pd(PPh3)2Cl2]
Precious Metals Chemistry
PMC
Umicore CX21
478980-03-9[(IPr)Pd(allyl)CI]
Precious Metals Chemistry
PMC
Umicore CX93
72287-26-4[Pd(dppf)Cl2]
Precious Metals Chemistry
PMC
[Pd2(dba)3] x dba
51364-51-3[Pd2(dba)3] x dba
Precious Metals Chemistry
PMC
[Pd(C6H5CN)2Cl2]
14220-64-5[Pd(C6H5CN)2Cl2]
Precious Metals Chemistry
PMC
Umicore CX94
95464-05-4[Pd(dppf)Cl2] x CH2Cl2
Precious Metals Chemistry
PMC
[Pd(acac)2]
14024-61-4[Pd(acac)2]
Precious Metals Chemistry
PMC
Umicore CX95
851232-71-8[Pd(dppf)Cl2] x (CH3)2CO
Precious Metals Chemistry
PMC