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Business unit / dept.: Precious Metals Chemistry

Umicore CX201

Umicore CX201

Chloro(1-tert-butyl-1H-inden-1-yl)(tri-tert-butylphosphine)palladium(II)

CAS Number: 1779569-15-1

Chemical properties

Chemical formula

C25H42ClPPd

Empirical formula

[Pd(1-tBu-Ind)(P(tBu)3)Cl]

Molecular weight

515.45

Metal

Pd

Theoretical metal content

21

Metal purity

99.95

Your contact person

Yukari Nakada

T: +81 90 9018 6731
Email

Heidi Heuser

T: +49 6181 706 4787
Email

Don Zeng

T: +1 (714) 777 3737
Email

Chinmay Pandya

T: +91 9867662944
Email

Heidi Heuser

T: +49 6181 706 4787
Email

Please order your research quantities at Merck / MilliporeSigma

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Applications & references

Description

Suzuki-Miyaura coupling reaction of both linear and cyclic alkyl trifluoroboronates salts and various aryl chlorides, including an example of a nitrogen-containing heterocycle.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

 

Firstly reported Hiyama-Denmark reactions using aryl silanolates as nucleophiles as an alternative to Suzuki-Miyaura reactions.

Reference: Org. Lett. 2016, 18, 5784 (DOI: 10.1021/acs.orglett.6b02330)

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