Skip to main content Skip to primary navigation

Grubbs Catalyst® M202

Grubbs Catalyst® M202

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II)

CAS Number: 536724-67-1

Chemical properties

Chemical formula

C54H69N2Cl2PRu

Empirical formula

(SIMes)Ru(PCy3)(Ind)Cl2

Molecular weight

949.10

Metal

Ru

Theoretical metal content

11

Physical state

powder

Color

red brown

Metal purity

99.9

Your contact person

Yukari Nakada

T: +81 90 9018 6731
Email

Chinmay Pandya

T: +91 9867662944
Email

Don Zeng

T: +1 (714) 777 3737
Email

Heidi Heuser

T: +49 6181 706 4787
Email

Ula Rao

T: +86 (21) 2411 6843
Email

Heidi Heuser

T: +49 6181 706 4787
Email

Please order your research quantities at Merck / MilliporeSigma

Applications & references

Description

Cross metathesis of terpenoids.

Reference: WO2012 004414

 

Preparation of α,ω-diacids starting from methyl oleate via self metathesis.

Reference: WO2010 020368

 

Cross metathesis of (E)-ethyl 2-isopropylpenta-2,4-dienoate for the synthesis of pharmaceutical active compounds , in particular rennin inhibitors.

Reference: WO2008 155338

 

Ring closing metathesis in the total synthesis of desoxyepothilone derivatives, which inhibit the growth of tumor cells.

Reference: WO2006 111491

 

Challenging ring closing metathesis.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

 

Enyne cycloisomerization.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

 

Enyne ring closing metathesis.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

 

Cross metathesis of functionalized alkenes.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

 

Ring rearrangement metathesis.

Reference: Eur. J. Org. Chem.  2010, 937 (DOI: 10.1002/ejoc.200901316)

 

Related products

Hoveyda Grubbs Catalyst® M720

301224-40-8

Precious Metals Chemistry

PMC

Grubbs Catalyst® M220

1255536-61-8[(SIMes)Ru(P(OiPr)3)(Ind)Cl2]

Precious Metals Chemistry

PMC

Grubbs Catalyst® M102

172222-30-9Ru(PCy3)2(benzylidene)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M350

934538-12-2 

Precious Metals Chemistry

PMC

Grubbs Catalyst® M800

1383684-54-5(SIMes)2Ru(Ind)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M110

894423-99-5Ru(iBu-phobane)2(Ind)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M103

194659-03-5Ru(PCy3)2(butenylidene)Cl2

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M722

635679-24-2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M204

246047-72-3(SIMes)Ru(PCy3)(benzylidene)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M206

373640-75-6(SIPr)Ru(PCy3)(benzylidene)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M201

1307233-23-3(SIPr)Ru(PPh3)(Ind)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M104

1190427-44-1Ru(PCy3)2(2-thienylmethylene)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M310

1031262-76-6[(SIMes)Ru(py)(Ind)Cl2]

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M731

1212009-05-6 

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M2001

1352916-84-7

Precious Metals Chemistry

PMC

Grubbs Catalyst® M208

1190427-50-9[(Me)2-IMes]Ru(PCy3)(2-thienylmethylene)Cl2

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M730

1025728-57-7 

Precious Metals Chemistry

PMC

Grubbs Catalyst® M200

340810-50-6[(SIMes)Ru(PPh3)(Ind)Cl2]

Precious Metals Chemistry

PMC

Grubbs Catalyst® M209

1190427-49-6(IMes)Ru(PCy3)(2-thienylmethylene)Cl2

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M710

1025728-56-6 

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M711

1212008-99-5 

Precious Metals Chemistry

PMC

Grubbs Catalyst® M203

254972-49-1(IMes)Ru(PCy3)(Ind)Cl2

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M700

203714-71-0

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M721

927429-61-6

Precious Metals Chemistry

PMC

Grubbs Catalyst® M101 Ultrapure

250220-36-1Ru(PCy3)2(Ind)Cl2

Precious Metals Chemistry

PMC

Grubbs Catalyst® M801

508172-19-8(SIMes)2Ru(benzylidene)Cl2

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M1002

1206687-43-5

Precious Metals Chemistry

PMC

Hoveyda Grubbs Catalyst® M1001

1632041-02-1

Precious Metals Chemistry

PMC

Grubbs Catalyst® M207

253688-91-4(SIMes)Ru(PCy3)(butenylidene)Cl2

Precious Metals Chemistry

PMC