Fu catalyst

Bis(tri-tert-butylphosphine)palladium(0)

CAS Number: 53199-31-8

Product class: M-P, Homogeneous Catalysts, M-C, Alkyl Ligands, Monodentate Ligands

Reaction type: Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Carbonylation, Mizoroki Heck Coupling Reaction, Negishi Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction

Applications & references

Diastereoselctive synthesis of isochromans using a Palladium catalyzed carboiodination.

Reference: Org. Lett. 2012, 14, 4806. (DOI: 10.1021/ol302111y)

High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl halides.

Reference: J. Org. Chem. 2010, 75, 6998. (DOI: 10.1021/jo101433g)

Arylation of hydrosiloxanes for the synthesis of symmetrical and unsymmetrical siloxanes. They are interesting substrates for the usage as liquid crystals, starting materials for cross coupling reactions and biologically active compounds.

Reference: Chem. Comm. 2013, 49, 11275. (DOI: 10.1039/c3cc46294c)