Fu catalyst

Fu catalyst

Bis(tri-tert-butylphosphine)palladium(0)

CAS Number: 53199-31-8

Product class: M-P, Homogeneous Catalysts, M-C, Alkyl Ligands, Monodentate Ligands

Reaction type: Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Carbonylation, Mizoroki Heck Coupling Reaction, Negishi Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction

Chemical properties

Chemical formula

C24H54P2Pd

Empirical formula

[Pd(P(tBu3))2]

Molecular weight

511.06

Metal

Pd

Theoretical metal content

21

Physical state

crystalline

Color

white

Metal purity

99.95

Applications & references

Diastereoselctive synthesis of isochromans using a Palladium catalyzed carboiodination.

Reference: Org. Lett. 2012, 14, 4806. (DOI: 10.1021/ol302111y)

 

High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl halides.

Reference: J. Org. Chem. 2010, 75, 6998. (DOI: 10.1021/jo101433g)

 

Arylation of hydrosiloxanes for the synthesis of symmetrical and unsymmetrical siloxanes. They are interesting substrates for the usage as liquid crystals, starting materials for cross coupling reactions and biologically active compounds.

Reference: Chem. Comm. 2013, 49, 11275. (DOI: 10.1039/c3cc46294c)