Chiralyst Rh640
Chiralyst Rh640
[((S,S)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)pentamethylcyclopentadienylrhodium(I)
CAS Number: 219944-99-7
Metal:
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Applications & references
Asymmetric reduction of α-sulfonyloxy acetophenone compound yielding an optically active 2-sulfonyloxy-1-phenylethanol derivative with high enantiomer excess.
Reference: WO2008 054155
Transfer hydrogenation of aromatic ß-ketoester for the synthesis of secondary aminoalcohols.
Reference: WO2005 028437
Asymmetric transfer hydrogenation of N-sulfonyl ketimine derivatives.
Reference: Tetrah. Asym. 2010, 21, 800 (DOI: 10.1016/j.tetasy.2010.04.047)
Asymmetric transfer hydrogenation of 2-tosyloxy-1-(4-hydroxyphenyl)ethanones derivatives leading to an efficient synthetic route of ß-adrenergic agonists.
Reference: Tetrah. Asym. 2007, 18, 2662 (DOI: 10.1016/j.tetasy.2007.10.046)
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