Chiralyst Ru802

Chiralyst Ru802

Diacetato[(R)-2,2‘-bis(diphenylphosphino)-6,6‘-dimethoxy-1,1‘-biphenyl]ruthenium(II)

CAS Number: 133519-04-7

Product class: M-P, Homogeneous Catalysts, M-O, Acetate Ligands, Phosphorus Ligands - Chiral

Reaction type: Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation

Chemical properties

Chemical formula

C42H38O6P2Ru

Empirical formula

Ru[(R)-MeO-BIPHEP](OAc)2

Molecular weight

801.78

Metal

Ru

Theoretical metal content

13

Physical state

powder

Color

yellow

Metal purity

99.95

Legal information

This complex is IP protected and sold on a "kg price IP included" model, please contact us for more information on our IP access.

Applications & references

Asymmetric hydrogenation of (Z)-methyl 3-amino-4-methoxy butenoate.

Reference: Org. Proc. Res. Dev. 2011, 15, 353 (DOI: 10.1021/op034181b)

Synthesis of (S)-fluoromethyldihydro-furan-2-one for the manufacture of pyrido[2,1-a]isoquinoline derivatives which are useful for treatment or prophylaxis of diseases.

Reference: WO2006 125728

Asymmetric hydrogenation of (3R,4R)-4-hydroxy-azepane-3-carboxylic acid ethyl ester for the synthesis of well-known pharmacologically active compounds, e.g. balanol.    

Reference: EP0802190

Asymmetric hydrogenation and enantioselective hydrogen-shift in prochiral allylic systems.

Reference: EP0398132