Chiralyst Ru1251

Chiralyst Ru1251

Diacetato[(R)-2,2‘-bis[di-(3,5-di-tert-butylphenyl)-phosphino]-6,6‘-dimethoxy-1,1‘-biphenyl]ruthenium(II)

CAS Number: 194497-14-8

Product class: M-P, Homogeneous Catalysts, M-O, Acetate Ligands, Phosphorus Ligands - Chiral

Reaction type: Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation

Chemical properties

Chemical formula

C74H102O6P2Ru

Empirical formula

Ru[(R)-3,5-t-Bu-MeO-BIPHEP](OAc)2

Molecular weight

1250.63

Metal

Ru

Theoretical metal content

8

Physical state

powder

Color

yellow green

Metal purity

99.95

Legal information

This complex is IP protected and sold on a "kg price IP included" model, please contact us for more information on our IP access.

Applications & references

Asymmetric hydrogenation of (Z)-methyl 3-amino-4-methoxy butenoate.

Reference: Org. Proc. Res. Dev. 2011, 15, 353 (DOI: 10.1021/op1002775)

Synthesis of (S)-fluoromethyldihydro-furan-2-one for the manufacture of pyrido[2,1-a]isoquinoline derivatives which are useful for treatment or prophylaxis of diseases.

Reference: WO2006 125728

Asymmetric hydrogenation of pyrone derivatives.

Reference: J. Org. Chem. 1999, 64, 5768 (DOI: 10.1021/jo982215l)

Asymmetric hydrogenation of methylcyclopentanone derivatives.

Reference: J. Org. Chem. 1999, 64, 5768  (DOI: 10.1021/jo982215l)