Chiralyst Ru843

Chiralyst Ru843

Diacetato[(S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

CAS Number: 261948-85-0

Product class: M-P, Homogeneous Catalysts, M-O, Acetate Ligands, Phosphorus Ligands - Chiral

Reaction type: Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation

Chemical properties

Chemical formula

C48H38O4P2Ru

Empirical formula

Ru[(S)-BINAP](OAc)2

Molecular weight

841.84

Metal

Ru

Theoretical metal content

12

Physical state

powder

Color

orange

Metal purity

99.95

Legal information

This complex is IP protected and sold on a "kg price IP included" model, please contact us for more information on our IP access.

Applications & references

Catalytic asymmetric hydrogenation of functionalized acrylic acid derivatives for the synthesis of pharmaceutically active substances.

Reference: US2005 0070714

Asymmetric hydrogenation of diketenes.

Reference: J. Org. Chem. 1995, 60, 357 (DOI: 10.1021/jo00107a014)

Asymmetric hydrogenation of five-membred a,b-unsaturated carbonyl compounds.

Reference: J. Org. Chem. 1995, 60, 357 (DOI: 10.1021/jo00107a014)

Hydroxyl directed hydrogenation in the total synthesis of zaragozic acids.

Reference: Chem. Eur. J. 2011, 17, 3335 (DOI: 10.1002/chem.201003399)

Asymmetric hydrogenation toward the general asymmetric synthesis of isoquinoline alkaloids, e.g. morphine.

Reference: Tetrah. 2006, 62, 5448 (DOI: 10.1016/j.tet.2006.03.055)