Chiralyst Ru929

Chiralyst Ru929

Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride

CAS Number: 145926-28-9

Product class: M-P, Homogeneous Catalysts, M-C, Arene/Aryl Ligands, Phosphorus Ligands - Chiral

Reaction type: Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation

Chemical properties

Chemical formula

C54H46Cl2P2Ru

Empirical formula

[RuCl(p-cymene)(R)-BINAP]Cl

Molecular weight

928.88

Metal

Ru

Theoretical metal content

11

Physical state

powder

Color

red orange

Metal purity

99.95

Legal information

This complex is IP protected and sold on a "kg price IP included" model, please contact us for more information on our IP access.

Applications & references

Synthesis of chiral acid derivatives by asymmetrical hydrogenation of the corresponding (E)-allylic ethers in the preparation of spiro-substituted glutaramide derivatives.

Reference: EP644176

Asymmetric hydrogenation of halogenated acetophenones to enantiomerically pure halogenated phenyl ethanol derivatives.

Reference: Cat. Lett. 1996, 41, 111 (DOI: 10.1007/BF00811721)

Highly enantioselective catalytic hydrogenation of methyl-N-tertbutyl-3-oxoglutarate as a key step in the total synthesis of rovastatin.

Reference: Tetrah. Lett. 2008, 49, 4836 (DOI: 10.1016/j.tetlet.2008.06.018)

Enantioselective hydrogenation of 4-(hydroxymethyl)furan-2(5H)-one derivatives.

Reference: J. Mol. Cat. A: Chem. 2006, 259, 103 (DOI: 10.1016/j.molcata.2006.05.066)