Chiralyst Ru842

Chiralyst Ru842

Diacetato[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

CAS Number: 325146-81-4

Product class: M-P, Homogeneous Catalysts, M-O, Acetate Ligands, Phosphorus Ligands - Chiral

Reaction type: Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation

Chemical properties

Chemical formula

C48H38O4P2Ru

Empirical formula

Ru[(R)-BINAP](OAc)2

Molecular weight

841.84

Metal

Ru

Theoretical metal content

12

Physical state

powder

Color

tan

Metal purity

99.95

Legal information

This complex is IP protected and sold on a "kg price IP included" model, please contact us for more information on our IP access.

Applications & references

Asymmetric hydrogenation of ß-ketoester for the enantioselective synthesis of (R)-d-lactones.

Reference: WO2001 057014

Enantioselective synthesis of levetiracetam including asymmetric hydrogenation of (Z)-2-(2-oxopyrrolidin-1-yl)but-2-enamide.  

Reference: WO2001 064637

Synthesis of (S)-fluoromethyldihydro-furan-2-one for the manufacture of pyrido[2,1-a]isoquinoline derivatives which are useful for treatment or prophylaxis of diseases.

Reference: WO2006 125728

Asymmetric hydrogenation of five-membred a,b-unsaturated carbonyl compounds.

Reference: J. Org. Chem. 1995, 60, 357 (DOI: 10.1021/jo00107a014)