[Pd2(dba)3] x dba

[Pd2(dba)3] x dba

Tris(dibenzylideneacetone)dipalladium(0)

CAS Number: 51364-51-3

Product class: Homogeneous Catalysts, M-C, Diene/Dienyl Ligands

Reaction type: Amination, Buchwald-Hartwig Aminaton, Carbonylation, Cross Coupling Reactions with Arenes, Mizoroki Heck Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction, Oxidation, Reduction

Chemical properties
Chemical formula

C51H42O3Pd2

Empirical formula

[Pd2(dba)3] x dba

Molecular weight

915.73

Metal

Pd

Theoretical metal content

16

Physical state

crystalline

Color

dark purple

Metal purity

99.95

Applications & references

Palladium catalyzed conversion of aryl chlorides and triflates to nitroaromatics.

 

Reference: J. Am. Chem. Soc. 2009, 131, 12898 (DOI: 10.1021/ja905768k)

Site selective sp³ palladium catalyzed direct arylation for a rapid derivatization of heterocyclic compounds.

 

Reference: J. Am. Chem. Soc. 2008, 130, 3266. (DOI: 10.1021/ja710451s)

One-pot ketoindoline synthesis by Palladium catalyzed g-arylation of b,g-unsaturated ketones.

 

Reference: Angew. Chem. Int. Ed. 2008, 47, 177. (DOI: 10.1002/anie.200704529)

Asymmetric synthesis of indolines by Palladium catalyzed arylation of b,g-unsaturated ketones.

Reference: Angew. Chem. Int. Ed. 2008, 47, 177. (DOI: 10.1002/anie.200704529)

Suzuki cross coupling of aryl chorides with arylboronic acids.

Reference: Angew. Chem. Int. Ed. 1998, 37, 3387. (DOI: 10.1002/(SICI)1521-3773(19981231)37:24<3387::AID-ANIE3387>3.0.CO;2-P)

Efficient method for Suzuki-Miyaura reaction of lithium triisopropyl 2-pyridylborates and aryl chlorides.

 

Reference: Angew. Chem. Int. Ed. 2008, 48, 4695. (DOI: 10.1002/anie.200801465)

Palladium catalyzed aminocarbonylation of aryl halides.

 

Reference: J. Am. Chem. Soc. 2013, 135, 16841. (DOI: 10.1021/ja4098093)

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