Umicore Hoveyda-Grubbs Catalyst M711

Umicore Hoveyda-Grubbs Catalyst M711

[1,3-Bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]dichloro[(2-isopropoxy)(5-trifluoroacetamido)benzylidene]ruthenium(II)

CAS Number: 1212008-99-5

Product class: M-O, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands, M-C, Hoveyda-Grubbs Catalyst® 2nd Generation, SIPr, Alkoxybenzylidene Ligands

Reaction type: Alkene Metathesis, Cross Metathesis, Ring Closing Metathesis, Self Metathesis

Chemical properties

Chemical formula

C39H50N3Cl2F3O2Ru

Molecular weight

821.81

Metal

Ru

Theoretical metal content

12

Physical state

powder

Color

green

Metal purity

99.95

Legal information

WO 2008 034552 applies.

Applications & references

Cross metathesis of terpenoids.

Reference: WO2012 004414

 

Ring closing metathesis of functionalized α,ω-dienes.

Reference: Eur. J. Org. Chem. 2009, 4254 (DOI: 10.1002/ejoc.200900407)

 

Ring closing metathesis of functionalized enynes.

Reference: Eur. J. Org. Chem. 2009, 4254 (DOI: 10.1002/ejoc.200900407)

 

Cross metathesis with methyl acrylate.

Reference: Eur. J. Org. Chem. 2009, 4254 (DOI: 10.1002/ejoc.200900407)

 

Formation of trisubstituted alkenes via cross metathesis.

Reference: Eur. J. Org. Chem. 2009, 4254 (DOI: 10.1002/ejoc.200900407)

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