Umicore Grubbs Catalyst M202

Umicore Grubbs Catalyst M202

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II)

CAS Number: 536724-67-1

Product class: M-P, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands, M-C, Grubbs Catalyst® 2nd Generation, SIMes, Phosphorus Ligands - Achiral

Reaction type: Alkene Metathesis, Cross Metathesis, Enyne Metathesis, Ring Arrangement Metathesis , Ring Closing Metathesis, Self Metathesis

Chemical properties
Chemical formula

C54H69N2Cl2PRu

Empirical formula

(SIMes)Ru(PCy3)(Ind)Cl2

Molecular weight

949.10

Metal

Ru

Theoretical metal content

11

Physical state

powder

Color

red brown

Metal purity

99.95

Legal information

WO 2000 15339, US 10 873 026 and foreign equivalents apply. For use in pharmaceutical applications.

Applications & references

Cross metathesis of terpenoids.

Reference: WO2012 004414

Preparation of a,w-diacids starting from methyl oleate via self metathesis.

Reference: WO2010 020368

Cross metathesis of (E)-ethyl 2-isopropylpenta-2,4-dienoate for the synthesis of pharmaceutical active compounds , in particular rennin inhibitors.

Reference: WO2008 155338

Ring closing metathesis in the total synthesis of desoxyepothilone derivatives, which inhibit the growth of tumor cells.

Reference: WO2006 111491

Challenging ring closing metathesis.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

Enyne cycloisomerization.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

Enyne ring closing metathesis.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

Cross metathesis of functionalized alkenes.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

Ring rearrangement metathesis.

Reference: Eur. J. Org. Chem.  2010, 937 (DOI: 10.1002/ejoc.200901316)

 

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