Umicore Grubbs Catalyst M202

Umicore Grubbs Catalyst M202

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II)

CAS Number: 536724-67-1

Product class: M-P, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands, M-C, Grubbs Catalyst® 2nd Generation, SIMes, Phosphorus Ligands - Achiral

Reaction type: Alkene Metathesis, Cross Metathesis, Enyne Metathesis, Ring Arrangement Metathesis , Ring Closing Metathesis, Self Metathesis

Chemical properties
Chemical formula

C54H69N2Cl2PRu

Empirical formula

(SIMes)Ru(PCy3)(Ind)Cl2

Molecular weight

949.10

Metal

Ru

Theoretical metal content

11

Physical state

powder

Color

red brown

Metal purity

99.95

Legal information

WO 2000 15339, US 10 873 026 and foreign equivalents apply. For use in pharmaceutical applications.

Applications & references

Cross metathesis of terpenoids.

Reference: WO2012 004414

Preparation of a,w-diacids starting from methyl oleate via self metathesis.

Reference: WO2010 020368

Cross metathesis of (E)-ethyl 2-isopropylpenta-2,4-dienoate for the synthesis of pharmaceutical active compounds , in particular rennin inhibitors.

Reference: WO2008 155338

Ring closing metathesis in the total synthesis of desoxyepothilone derivatives, which inhibit the growth of tumor cells.

Reference: WO2006 111491

Challenging ring closing metathesis.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

Enyne cycloisomerization.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

Enyne ring closing metathesis.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

Cross metathesis of functionalized alkenes.

Reference: Chem. Eur. J. 2008, 14, 806 (DOI: 10.1002/chem.200701340)

Ring rearrangement metathesis.

Reference: Eur. J. Org. Chem.  2010, 937 (DOI: 10.1002/ejoc.200901316)

 

Request a quote or MSDS

Related products

Umicore Hoveyda-Grubbs Catalyst M720

PMC Product

301224-40-8

Precious Metals Chemistry

Umicore Hoveyda-Grubbs Catalyst M731

PMC Product

1212009-05-6 

Precious Metals Chemistry

Umicore Hoveyda-Grubbs Catalyst M722

PMC Product

635679-24-2

Precious Metals Chemistry

Umicore Hoveyda-Grubbs Catalyst M2001

PMC Product

1352916-84-7

Precious Metals Chemistry

Umicore Grubbs Catalyst M201

PMC Product

1307233-23-3(SIPr)Ru(PPh3)(Ind)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M206

PMC Product

373640-75-6(SIPr)Ru(PCy3)(benzylidene)Cl2

Precious Metals Chemistry

Umicore Hoveyda-Grubbs Catalyst M730

PMC Product

1025728-57-7 

Precious Metals Chemistry

Umicore Grubbs Catalyst M104

PMC Product

1190427-44-1Ru(PCy3)2(2-thienylmethylene)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M310

PMC Product

1031262-76-6[(SIMes)Ru(py)(Ind)Cl2]

Precious Metals Chemistry

Umicore Grubbs Catalyst M800

PMC Product

1383684-54-5(SIMes)2Ru(Ind)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M200

PMC Product

340810-50-6[(SIMes)Ru(PPh3)(Ind)Cl2]

Precious Metals Chemistry

Umicore Grubbs Catalyst M102

PMC Product

172222-30-9Ru(PCy3)2(benzylidene)Cl2

Precious Metals Chemistry

Umicore Hoveyda-Grubbs Catalyst M710

PMC Product

1025728-56-6 

Precious Metals Chemistry

Umicore Grubbs Catalyst M203

PMC Product

254972-49-1(IMes)Ru(PCy3)(Ind)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M220

PMC Product

1255536-61-8[(SIMes)Ru(P(OiPr)3)(Ind)Cl2]

Precious Metals Chemistry

Umicore Grubbs Catalyst M103

PMC Product

194659-03-5Ru(PCy3)2(butenylidene)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M350

PMC Product

934538-12-2 

Precious Metals Chemistry

Umicore Grubbs Catalyst M209

PMC Product

1190427-49-6(IMes)Ru(PCy3)(2-thienylmethylene)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M110

PMC Product

894423-99-5Ru(iBu-phobane)2(Ind)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M204

PMC Product

246047-72-3(SIMes)Ru(PCy3)(benzylidene)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M207

PMC Product

253688-91-4(SIMes)Ru(PCy3)(butenylidene)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M208

PMC Product

1190427-50-9[(Me)2-IMes]Ru(PCy3)(2-thienylmethylene)Cl2

Precious Metals Chemistry