Umicore Grubbs Catalyst M200

Umicore Grubbs Catalyst M200

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(3-phenyl-1H-inden-1-ylidene)(triphenylphosphine)ruthenium(II)

CAS Number: 340810-50-6

Product class: Homogeneous Catalysts, Grubbs Catalyst® 2nd Generation, M-C, N-Heterocyclic Carbene Ligands, SIMes, M-P, Phosphorus Ligands - Achiral

Reaction type: Alkene Metathesis, Cross Metathesis, Enyne Metathesis, Ring Arrangement Metathesis , Ring Closing Metathesis, Ring Opening Metathesis Polymerization, Self Metathesis

Chemical properties
Chemical formula

C54H51N2Cl2PRu

Empirical formula

[(SIMes)Ru(PPh3)(Ind)Cl2]

Molecular weight

930.96

Metal

Ru

Theoretical metal content

11

Physical state

powder

Color

red brown

Metal purity

99.95

Legal information

WO 2000 15339, US 10 873 026 and foreign equivalents apply. For use in pharmaceutical applications.

Applications & references

Ring closing metathesis of enynes.

Reference: Chem. Eur. J. 2010, 16, 9215 (DOI: 10.1002/chem.201000659)

Ring closing metathesis in the synthesis of trisubstituted C-C double bonds.

Reference: Chem. Eur. J. 2010, 16, 9215 (DOI: 10.1002/chem.201000659)

Ring closing metathesis forming nitrogen containing heterocycles.

Reference: Chem. Eur. J. 2010, 16, 9215 (DOI: 10.1002/chem.201000659)

Ring-rearrangement metathesis.

Reference: Chem. Eur. J. 2010, 16, 9215 (DOI: 10.1002/chem.201000659)

Cross metathesis of fatty acids with but-3-en-2-one.

Reference: Chem. Eur. J. 2010, 16, 9215 (DOI: 10.1002/chem.201000659)

Ring opening metathesis polymerization.

Reference: Chem. Eur. J. 2010, 16, 9215 (DOI: 10.1002/chem.201000659)

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