Umicore Grubbs Catalyst M110

Umicore Grubbs Catalyst M110

Dichlorobis(isobutylphobane)(3-phenyl-1H-indenylidene)ruthenium(II)

CAS Number: 894423-99-5

Product class: Homogeneous Catalysts, Grubbs Catalyst® 1st Generation, M-P, Phosphorus Ligands - Achiral

Reaction type: Alkene Metathesis, Cross Metathesis, Enyne Metathesis, Ring Closing Metathesis, Ring Opening Metathesis Polymerization, Self Metathesis

Chemical properties
Chemical formula

C39H56Cl2P2Ru

Empirical formula

Ru(iBu-phobane)2(Ind)Cl2

Molecular weight

758.79

Metal

Ru

Theoretical metal content

13

Physical state

powder

Color

brown

Metal purity

99.95

Legal information

WO 2007 010453 applies.

Applications & references

Total synthesis of macrocyclic HCV protease inhibitor with RCM as key step.

Reference: US2009 0163706

Ring opening metathesis polymerization.

Reference: Adv. Synth. Catal. 2010, 352, 1934 (DOI: 10.1002/adsc.201000207)

Ring closing metathesis forming heterocycles.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

Enyne cycloisomerization.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

Ethenolysis of methyl oleate.

Reference: Chem. Comm. 2008, 2726 (DOI: 10.1039/B718287B)

Self metathesis of terminal alkenes.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

Request a quote or MSDS

Related products

Umicore Grubbs Catalyst M103

PMC

194659-03-5Ru(PCy3)2(butenylidene)Cl2

Precious Metals Chemistry

Umicore Hoveyda-Grubbs Catalyst M731

PMC

1212009-05-6 

Precious Metals Chemistry

Umicore Grubbs Catalyst M102

PMC

172222-30-9Ru(PCy3)2(benzylidene)Cl2

Precious Metals Chemistry

Umicore Hoveyda-Grubbs Catalyst M730

PMC

1025728-57-7 

Precious Metals Chemistry

Umicore Hoveyda-Grubbs Catalyst M722

PMC

635679-24-2

Precious Metals Chemistry

Umicore Hoveyda-Grubbs Catalyst M721

PMC

927429-61-6

Precious Metals Chemistry

Umicore Grubbs Catalyst M104

PMC

1190427-44-1Ru(PCy3)2(2-thienylmethylene)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M207

PMC

253688-91-4(SIMes)Ru(PCy3)(butenylidene)Cl2

Precious Metals Chemistry

Umicore Hoveyda-Grubbs Catalyst M2001

PMC

1352916-84-7

Precious Metals Chemistry

Umicore Grubbs Catalyst M350

PMC

934538-12-2 

Precious Metals Chemistry

Umicore Hoveyda-Grubbs Catalyst M710

PMC

1025728-56-6 

Precious Metals Chemistry

Umicore Grubbs Catalyst M205

PMC

927429-60-5[SI(o-Tol)]Ru(PCy3)(benzylidene)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M310

PMC

1031262-76-6[(SIMes)Ru(py)(Ind)Cl2]

Precious Metals Chemistry

Umicore Grubbs Catalyst M208

PMC

1190427-50-9[(Me)2-IMes]Ru(PCy3)(2-thienylmethylene)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M201

PMC

1307233-23-3(SIPr)Ru(PPh3)(Ind)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M209

PMC

1190427-49-6(IMes)Ru(PCy3)(2-thienylmethylene)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M203

PMC

254972-49-1(IMes)Ru(PCy3)(Ind)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M101

PMC

250220-36-1Ru(PCy3)2(Ind)Cl2

Precious Metals Chemistry

Umicore Grubbs Catalyst M800

PMC

1383684-54-5(SIMes)2Ru(Ind)Cl2

Precious Metals Chemistry

Umicore Hoveyda-Grubbs Catalyst M711

PMC

1212008-99-5 

Precious Metals Chemistry

Umicore Grubbs Catalyst M206

PMC

373640-75-6(SIPr)Ru(PCy3)(benzylidene)Cl2

Precious Metals Chemistry

Umicore Hoveyda-Grubbs Catalyst M720

PMC

301224-40-8

Precious Metals Chemistry

Umicore Grubbs Catalyst M220

PMC

1255536-61-8[(SIMes)Ru(P(OiPr)3)(Ind)Cl2]

Precious Metals Chemistry