Umicore Grubbs Catalyst M110

Umicore Grubbs Catalyst M110

Dichlorobis(isobutylphobane)(3-phenyl-1H-indenylidene)ruthenium(II)

CAS Number: 894423-99-5

Product class: Homogeneous Catalysts, Grubbs Catalyst® 1st Generation, M-P, Phosphorus Ligands - Achiral

Reaction type: Alkene Metathesis, Cross Metathesis, Enyne Metathesis, Ring Closing Metathesis, Ring Opening Metathesis Polymerization, Self Metathesis

Chemical properties
Chemical formula

C39H56Cl2P2Ru

Empirical formula

Ru(iBu-phobane)2(Ind)Cl2

Molecular weight

758.79

Metal

Ru

Theoretical metal content

13

Physical state

powder

Color

brown

Metal purity

99.95

Legal information

WO 2007 010453 applies.

Applications & references

Total synthesis of macrocyclic HCV protease inhibitor with RCM as key step.

Reference: US2009 0163706

Ring opening metathesis polymerization.

Reference: Adv. Synth. Catal. 2010, 352, 1934 (DOI: 10.1002/adsc.201000207)

Ring closing metathesis forming heterocycles.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

Enyne cycloisomerization.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

Ethenolysis of methyl oleate.

Reference: Chem. Comm. 2008, 2726 (DOI: 10.1039/B718287B)

Self metathesis of terminal alkenes.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

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