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Grubbs Catalyst® M101

Grubbs Catalyst® M101

Dichloro(3-phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II)

CAS Number: 250220-36-1

Chemical properties

Chemical formula

C51H76Cl2P2Ru

Empirical formula

Ru(PCy3)2(Ind)Cl2

Molecular weight

923.08

Metal

Ru

Theoretical metal content

11

Physical state

powder

Color

brown

Metal purity

99.9

Your contact person

Ula Rao

T: +86 (21) 2411 6843
Email

Chinmay Pandya

T: +91 9867662944
Email

Phil Chalabi

T: +1 (918) 266 4826
Email

Heidi Heuser

T: +49 (6181) 59 2413
Email

Yukari Nakada

T: +81 90 9018 6731
Email

Heidi Heuser

T: +49 (6181) 59 2413
Email

Please order your research quantities at Merck / MilliporeSigma

Applications & references

Description

Total synthesis of macrocyclic HCV protease inhibitor with RCM as key step.

Reference: US2009 0163706

 

Metathesis key step in the synthesis of cyclic tripyrole pigment nonylprodigiosin.

Reference: J. Org. Chem. 1999, 64, 8275 (DOI: 10.1021/jo991021i)

 

Total synthesis of macrocyclic compounds which are useful as inhibitors of hepatitis C virus N33 protease.

Reference: US2007 0027071

 

Macrocyclization step by ring closing metathesis in the synthesis of turrianes.

Reference: Chem. Eur. J. 2002, 8, 1856 (10.1002/1521-3765(20020415)8:8<1856::AID-CHEM1856>3.0.CO;2-RView)

 

Ring closing metathesis.   

Reference: Chem. Comm. 2008, 2726 (DOI: 10.1039/B718287B)

                

Enyne cycloisomerization.    

Reference: Chem. Comm. 2008, 2726 (DOI: 10.1039/B718287B)

 

Nucleophilic addition of acids to alkynes.

Reference: Chem. Comm. 2008, 2726 (DOI: 10.1039/B718287B)

 

Diastereoselective double ring closing metathesis.

Reference: Chem. Comm. 2008, 2726 (DOI: 10.1039/B718287B) 

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