Umicore Hoveyda-Grubbs Catalyst M720

Umicore Hoveyda-Grubbs Catalyst M720

[1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(2-isopropoxybenzylidene)ruthenium(II)

CAS Number: 301224-40-8

Product class: Carbene Ligands, M-C, Homogeneous Catalysts, Grubbs Catalyst® 2nd Generation, Alkoxybenzylidene Ligands

Reaction type: Alkene Metathesis, Acyclic Diene Metathesis, Cross Metathesis, Ring Arrangement Metathesis , Ring Closing Metathesis, Ring Opening Metathesis Polymerization, Self Metathesis

Chemical properties

Chemical formula

C31H38Cl2N2ORu

Empirical formula


Molecular weight

626.62

Metal

Ru

Theoretical metal content

16

Physical state

powder

Color

green

Metal purity

99.95

Applications & references

Access to 3-oxindoles from Allylic Alcohols and Indoles.

Reference: Chemistry a European Journal, March 2018

 

Asymmetric Total Synthesis of Lancifodilactone G Acetate.

Reference: The Journal of Organic Chemistry, March 2018

 

Preparation of Functionalized α,β-Unsaturated Sulfonamides via Olefin Cross-Metathesis.

Reference: Org. Lett. 2020, 22, 13, 4970–4973

 

Formal Synthesis of (±)-Aplykurodinone-1 Based on the Indium-Catalyzed Conia-Ene Reaction.

Reference: Synlett 2020; 31(14): 1404-1408

 

Polymer Chain Editing: Functionality 'Knock-in', 'Knock-out' and Replacement via Cross Metathesis Reaction and Thiol-Michael Addition.

Reference: Polym. Chem. 2020,11, 4807-4817

 

Selectively Depolymerizable Polyurethanes from Unsaturated Polyols Cleavable by Olefin Metathesis.

Reference: Macromol Rapid Commun 2020 ASAP (DOI: 10.1002/marc.202000571)