[Pd(OAc)2]3

Palladium(II) acetate

[Pd(OAc)2]3

Chemical properties

Chemical formula

C12H18O12Pd3

Empirical formula

[Pd(OAc)2]3

Molecular weight [g/mol]

673.53

Metal

Pd

Theoretical metal content [%]

47

Physical state

powder

Color

red brown

Metal purity [%]

99.95

Safety Information

H318, H413

Handling & storage information

Handling information

Ensure good ventilation and exhaustion at the workplace.


Storage information

Do not store above 25°C (77°F). Store in a tightly closed original container, protected from direct sunlight in a dry, cool and well-ventilated area.

Applications & References

Synthesis of 2-(4-{2-[(2R)-2-Cyclopentyl-5-(5,7-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-2-ylmethyl)-4-hydroxy-6-oxo-3,6-dihydro-2H-pyran-2-yl]-ethyl}-2-fluoro-phenyl)-2-methyl-propionitrile on multikilogram scale using a merging Heck coupling reaction. Compound is an inhibitor of the hepatitis C viral polymerase (HCVP) enzyme.

Reference: Org. Proc. Res. Dev. 2006, 10, 814. (DOI: 10.1021/op0600761)

Reductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.

Reference: Org. Proc. Res. Dev. 2007, 11, 39. (DOI: 10.1021/op060193w),

Synthesis of the pyrazolopyridinone-based p38 mitogen-activated protein kinase inhibitor including a Suzuki coupling reaction. p38 MAP kinases are intercellular serine/threonine kinases which certainly regulate the production and action of several pro-inflammatory mediators. They are also involved in disease states such as rheumatoid arthritis, Crohn’s diseases and psoriasis.

Reference: Org. Proc. Res. Dev. 2011, 15, 31. (DOI: 10.1021/op100205s)

Efficient hydroformylation of aryl triflates.

Reference: Synthesis 1996, 470 (DOI: 10.1055/s-1996-4246)

Deacetylation-Diazotation-Heck-Sequence: Carbon-Carbon bond formation with acetanilides as formal leaving groups.

Reference: Adv. Synth. Catal. 2013, 355, 463 (DOI: 10.1002/adsc.201200929)

Deacetylation-Diazotation-Suzuki-Sequence: Carbon-Carbon bond formation with acetanilides as formal leaving groups.

Reference: Adv. Synth. Catal. 2013, 355, 463 (DOI: 10.1002/adsc.201200929)

Deacetylation-Diazotation-[2+2+1]-Cycloaddition:

Reference: Adv. Synth. Catal. 2013, 355, 463 (DOI: 10.1002/adsc.201200929)

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