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Chiralyst® Ru842

Chiralyst® Ru842

Diacetato[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

CAS Number: 325146-81-4

Chemical properties

Chemical formula

C48H38O4P2Ru

Empirical formula

Ru[(R)-BINAP](OAc)2

Molecular weight

841.84

Metal

Ru

Theoretical metal content

12

Physical state

powder

Color

brownish

Metal purity

99.9

Your contact person

Heidi Heuser

T: +49 (6181) 59 2413
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Ula Rao

T: +86 (21) 2411 6843
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Chinmay Pandya

T: +91 9867662944
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Yukari Nakada

T: +81 90 9018 6731
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Phil Chalabi

T: +1 (918) 266 4826
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Heidi Heuser

T: +49 (6181) 59 2413
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Applications & references

Description

Asymmetric hydrogenation of ß-ketoester for the enantioselective synthesis of (R)-d-lactones.

Reference: WO2001 057014

 

Enantioselective synthesis of levetiracetam including asymmetric hydrogenation of (Z)-2-(2-oxopyrrolidin-1-yl)but-2-enamide.  

Reference: WO2001 064637

 

Synthesis of (S)-fluoromethyldihydro-furan-2-one for the manufacture of pyrido[2,1-a]isoquinoline derivatives which are useful for treatment or prophylaxis of diseases.

Reference: WO2006 125728

 

Asymmetric hydrogenation of five-membred α,β-unsaturated carbonyl compounds.

Reference: J. Org. Chem. 1995, 60, 357 (DOI: 10.1021/jo00107a014)