Chiralyst Rh756

(1,5-Cyclooctadiene)[(R,R)-1,2-bis[(ortho-methoxyphenyl)(phenyl)phosphino]ethane]rhodium(I) tetrafluoroborate

[Rh[(R,R)-DIPAMP](cod)]BF4

Product Number : 3000036060     CAS Number : 56977-92-5
Product Keywords :

Chemical properties

Chemical formula

C36H40BF4O2P2Rh

Empirical formula

[Rh[(R,R)-DIPAMP](cod)]BF4

Molecular weight [g/mol]

756.37

Metal

Rh

Theoretical metal content [%]

14

Physical state

crystalline

Color

yellow orange

Metal purity [%]

99.95

Safety Information

H228, H290, H302, H332, H312, H314, H318, H413

Handling & storage information

Handling information

Avoid formation of respirable particles. Do not breathe vapors/dust. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Avoid dust formation. Provide appropriate exhaust ventilation at places where dust is formed. Keep away from open flames, hot surfaces and sources of ignition.


Storage information

Do not store above 25°C (77°F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.

Applications & References

Legal information

This complex is IP protected and sold on a "kg price IP included" model, please contact us for more information on our IP access.

Preparation of (S)-N-acetylcolchinol by asymmetrical hydrogenation of the corresponding enamine. Colchinol derivatives are useful for the treatment of diseases involving angiogenesis.

Reference: WO2006 067412

Synthesis of a-arylpropionic acids by catalytic asymmetrical hydrogenation of a-arylpropenioc acids starting from a-arylketones. 

Reference: WO909552

Intramolecular addition of amines to alkynes.

Reference: Tetrah. Lett. 1998, 39, 5961 (DOI: 10.1016/S0040-4039(98)01217-9)

Asymmetric hydrogenation reaction of an intermediate product in the synthesis of a N-Boc-phenylalanine pharmaceutical intermediate.

Reference: Org. Proc. Res. Proc. 2011, 15, 1163 (DOI: 10.1021/op200129m)

Synthesis of (2-pyridyl)alanines via asymmetric hydrogenation.

Reference: Org. Lett. 2001, 3, 3157 (DOI: 10.1021/ol016455q)

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